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学校录入文章，急求文章入藏号，拜托拜托 The Preparation and Analysis of Chlorinated Ethylene Vinyl Acetate Copolymer as Coating Film in Gas-Solid Phase, Journal of applied polymer science, 2014,131(22) DOI: 10.1002/app.41093 |
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2楼2014-11-11 16:25:14
baiyuefei
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3楼2014-11-11 16:28:58
baiyuefei
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【答案】应助回帖
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珊瑚贝贝: 金币+10, ★★★★★最佳答案, 谢谢啦 2014-11-12 08:23:10
oven1986: LS-EPI+1, 感谢应助！ 2014-11-12 15:27:43
珊瑚贝贝: 金币+10, ★★★★★最佳答案, 谢谢啦 2014-11-12 08:23:10
oven1986: LS-EPI+1, 感谢应助！ 2014-11-12 15:27:43
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The Preparation and Analysis of Chlorinated Ethylene Vinyl Acetate Copolymer as Coating Film in Gas-Solid Phase 作者:Jing, Z (Jing, Zhao)[ 1 ] ; Liu, LJ (Liu, Lijuan)[ 1 ] ; Zhang, SK (Zhang, Shukai)[ 1 ] ; Zhao, JR (Zhao, Jiruo)[ 1 ] ; Feng, Y (Feng, Ying)[ 1 ] JOURNAL OF APPLIED POLYMER SCIENCE 卷: 131 期: 22 文献号: 41093 DOI: 10.1002/APP.41093 出版年: NOV 15 2014 查看期刊信息 摘要 In this article, the feasibility of preparing chlorinated ethylene vinyl acetate copolymer (CEVA) in gas-solid phase is investigated. Furthermore, the structure of the chlorination product and its performance as a coating material are also analyzed. Both the molecular structure and crystallinity of the product are well studied with various characterization methods, including H-1-NMR, Fourier transform infrared, gel permeation chromatography, differential scanning calorimeter, and so forth. The results show that the chlorination of EVA in gas-solid phase is feasible and the chlorine content of CEVA can be made over 60%. It is also found that when the chlorine content is low, chlorination can easily occur in ethylene section but rarely happens in vinyl acetate section. Nevertheless, when the chlorine content of CEVA rises over 35%, -CH in the vinyl acetate section is also found chlorinated. The removal of hydrogen chloride is induced during chlorination, producing double bonds in the main chain. Besides, the trace of -CCl2 structure can also be found in the chain of CEVA. After chlorination, the crystallization will change and is negatively correlated with chlorine content. As the film forming material for coating, CEVA has its best performance with 50% chlorine content. (C) 2014 Wiley Periodicals, Inc. 关键词 作者关键词:addition polymerization; applications; coatings KeyWords Plus:CARBON NANOTUBE NANOCOMPOSITES; FLAME-RETARDANT BEHAVIOR 作者信息 通讯作者地址: Zhao, JR (通讯作者) Qingdao Univ Sci & Technol, Shandong Prov Key Lab Rubber Plast, Minist Educ, Key Lab Rubber Plast, Qingdao, Peoples R China. 地址: [ 1 ] Qingdao Univ Sci & Technol, Shandong Prov Key Lab Rubber Plast, Minist Educ, Key Lab Rubber Plast, Qingdao, Peoples R China 电子邮件地址:jiruozhao@qust.edu.cn 基金资助致谢 基金资助机构 授权号 National Natural Science Foundation of China 51173090 查看基金资助信息 出版商 WILEY-BLACKWELL, 111 RIVER ST, HOBOKEN 07030-5774, NJ USA 类别 / 分类 研究方向  olymer ScienceWeb of Science 类别 olymer Science文献信息 文献类型:Article 语种:English 入藏号: WOS:000341179900049 ISSN: 0021-8995 电子 ISSN: 1097-4628 期刊信息 Impact Factor (影响因子): Journal Citation Reports® 其他信息 IDS 号: AO2TW Web of Science 核心合集中的 "引用的参考文献": 10 Web of Science 核心合集中的 "被引频次": 0 |
4楼2014-11-11 16:29:15
baiyuefei
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- 贵宾: 46.97
- 金币: 659371
- 散金: 11616
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- 帖子: 69611
- 在线: 13513小时
- 虫号: 676696
- 注册: 2008-12-18
- 性别: GG
- 专业: 合成药物化学
- 管辖: 有机交流
5楼2014-11-11 16:29:26