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chemmtf

铜虫 (小有名气)

[求助] jpc修改稿审稿意见

The SOMOs, and not the HOMO’s as mentioned in the article and in the caption of supplementary material, of the triplet states displayed in figure S1 and the spin density represented in figure S-3 let me think that the holes of the triplet are not correctly identified. Du to spin repolarization effects in UDFT calculation, it is very scarce that SOMO-1 represents the hole. To my experience the hole of triplet states of similar complex is borne by deeper SOMO. To remove all doubts and to follow the discussion safely, the authors have to calculate Natural Orbitals.   这篇文章不涉及三重态的自旋密度,而审稿人坚持要做出三重态自旋密度图,三重态自旋密度图和三重态分子轨道图有什么关系,在修改稿中轨道图和自旋密度图已做过,为什么审稿人还要计算Natural Orbitals,如何计算Natural Orbitals?拜托各位了!
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2楼2014-06-21 20:23:10
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