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【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
rosarain(oven1986代发): 金币+10, 代扣结帖。 2014-06-13 10:39:25
oven1986: 检索EPI+1, 感谢应助！ 2014-06-13 10:39:32
Accession number:
20141117465484
Title:
Thermodynamic properties and solid-liquid phase equilibrium of bisphenol A-bis (5, 5-dimethyl-1,3-dioxaphosphorinanyl-2-oxyphosphate ester) in selected solvents
Authors:
Jiang, Lin-Kun1, 2; Wang, Li-Sheng1
Author affiliation:
1School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing, China
2Wuhai College, Inner Mongol University of Technology, Wuhai, China
Corresponding author:
Wang, L.-S.
Source title:
Journal of Chemical and Pharmaceutical Research
Abbreviated source title:
J. Chem. Pharm. Res.
Volume:
6
Issue:
2
Issue date:
2014
Publication year:
2014
Pages:
47-59
Language:
English
E-ISSN:
09757384
Document type:
Journal article (JA)
Publisher:
Journal of Chemical and Pharmaceutical Research
Abstract:
In this work, we investigated the thermodynamic properties of flame retardant bisphenol A-bis (5,5-dimethyl-1, 3-dioxaphosphorinanyl-2-oxy phosphate ester) (BADOPE), including the melting point and the enthalpy of fusion of BADOPE by differential scanning calorimeter (DSC) and the thermal stability of BADOPE by thermogravimetric analysis (TGA). BADOPE was synthesized and characterized by EA, FT-IR and 1HNMR. Using a static analytic method, solid-liquid phase equilibrium data (the solubility) of BADOPE in acetonitrile, acetone, methanol, tetrahydrofuran, ethanol, ethyl acetate, methylethylketone and 1,4-dioxane were obtained at temperatures ranging from 293 to 338 K. Several thermodynamic models, including the ideal, modified Apelblat, Wilson, NRTL, UNIQUAC and Scatchard-Hildebrand models, were applied to correlate the experimental solubility data.
Number of references:
28
Main heading:
Phase equilibria
Controlled terms:
Acetone - Differential scanning calorimetry - Esterification - Esters - Flame retardants - Oils and fats - Solubility - Synthesis (chemical) - Thermodynamic properties - Thermogravimetric analysis
Uncontrolled terms:
Differential scanning calorimeters - Enthalpy of fusion - Experimental solubility datum - Phosphate esters - Phosphorus-containing - Solid-liquid phase equilibria - Tetra-hydrofuran - Thermodynamic model
Classification code:
641.1 Thermodynamics - 801 Chemistry - 801.4 Physical Chemistry - 802.2 Chemical Reactions - 803 Chemical Agents and Basic Industrial Chemicals - 804.1 Organic Compounds
Database:
Compendex
Compilation and indexing terms, © 2013 Elsevier Inc. |
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