±±¾©Ê¯ÓÍ»¯¹¤Ñ§Ôº2026ÄêÑо¿ÉúÕÐÉú½ÓÊÕµ÷¼Á¹«¸æ
²é¿´: 906  |  »Ø¸´: 4
±¾Ìû²úÉú 1 ¸ö ·­ÒëEPI £¬µã»÷ÕâÀï½øÐв鿴
µ±Ç°Ö»ÏÔʾÂú×ãÖ¸¶¨Ìõ¼þµÄ»ØÌû£¬µã»÷ÕâÀï²é¿´±¾»°ÌâµÄËùÓлØÌû

loser

ľ³æ (СÓÐÃûÆø)

[ÇóÖú] Çë°ïÖúÈóɫһ¶Î»°

Figure 1 and 2 show that 0.6wt¡ë amount of iron existed on the fresh catalyst, which is from the raw materials for preparation of catalyst. The Fe component on the fresh catalyst has no negative effect on the hydroisomerization reaction, since Fe locates in the catalyst support bulk with an inert state. The Fe content after reaction increases remarkably to more than 1.2 wt¡ë, e.g., 2Kh and 8Kh in Figure 1 and 2. All the Fe species adsorbed during reactions locates on the catalyst surface with reduced or oxidized states. These Fe components on the surface will have a series of complicated negative effects on the surface acidic sites and metallic sites, or even plug the pores of catalysts after long time enrichment of Fe from reagent oils. Further more, the solid Fe deposits on the catalyst can hardly be removed no matter by reductive or oxidative treating method. So Fe species in the reagent oils must be removed before reaction.

» ²ÂÄãϲ»¶

ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

mac194

Ìú³æ (Ö°Òµ×÷¼Ò)

¡¾´ð°¸¡¿Ó¦Öú»ØÌû

¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï ¡ï
RXMCDM: ½ð±Ò+1, ¶àлӦ 2014-04-01 14:56:51
RXMCDM: ·­ÒëEPI+1 2014-04-02 10:37:29
RXMCDM: ½ð±Ò+30 2014-04-02 10:37:54
[ ¸Ðл½±ÉÍ ]
Because of the way it's prepared, fresh catalyst is held intact and protected especially on the outside by inert steel.  That outside layer (0.6wt¡ë as shown in Fig's 1 and 2) keeps acidic and metallic sites, especially those on the surface available for reaction.  Access to those sites can be reduced, sometimes completely if reactive iron were allowed to accumulate or even plug surface pores of the catalyst.  The catalyst can become useless once hydroisomerization or unchecked long-term contact with iron-rich reagent oils more than doubles superficial iron to 1.2 wt¡ë, or to 2Kh and 8Kh in Figures 1 and 2, respectively  Since solid iron deposits are nearly impossible to remove, reagent oils must be rid of its iron content as much as possible [prior to reaction] in order to preserve the catalyst.
¸½×¢:
  - ÈóɫĿµÄÊÇÒª±ÈÔ­ÎĸüÒ×¶Á,¸üÄÜÎüÒý¶ÁÕß, LZ Ô­ÒâÎÒÒÑÓÉÍâÈëÄÚ,¸ü¹ÊÊ»¯µÄ±í´ïÁË
  - ²»ÒªÍ»»»¶¯´Êʱ̬,³ý·Ç̸¼°ÊµÑ鵱ʱ,·ñÔòÒ»¹áÏÖÔÚʽ×îºÃ
  - ²¢·Ç "Figure 1, Figure 2" ²»¿É, "Fig's 1 and 2" ËõдҲÐÐ
  -  "with reduced or oxidized states" ±íʾ´øµç,ÒײúÉú·´Ó¦(¼´ "reactive"
  - "can hardly be removed no matter by ..." = "nearly impossible to remove"
  - Ô¤¼Æ"support bulk"  Ô­ÒâÊÇ  "±£³ÖÍêÕû" = "keep intact"
  - ·­Òë¼ÙÉè»îÐÔµãÔ½Äѽø,´ß»¯¼Á¾ÍÔ½²»ÖÐÓÃ
4Â¥2014-04-01 09:47:48
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
²é¿´È«²¿ 5 ¸ö»Ø´ð

ĵµ¤Ãç

Í­³æ (³õÈëÎÄ̳)

¡ï ¡ï ¡ï ¡ï ¡ï
RXMCDM: ½ð±Ò+1, ¶àлӦÖú£¡ 2014-03-31 22:20:30
loser: ½ð±Ò+34, ·­ÒëEPI+1, ¡ïÓаïÖú, 3 2014-04-02 08:37:59
RXMCDM: ·­ÒëEPI-1 2014-04-02 10:37:20
RXMCDM: ½ð±Ò-30 2014-04-02 10:37:42
Fig1 and Fig2 show that on the fresh catalyst there is a mixture of  0.6wt¡ë iron , which is from the raw materials ,The catalyst prepared by the raw materials.
ÀÖ¹Û£¬ÉÆÁ¼£¬µÍµ÷
2Â¥2014-03-31 22:09:54
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

RXMCDM

°æÖ÷ (ÎÄ̳¾«Ó¢)

ÓÅÐã°æÖ÷ÓÅÐã°æÖ÷ÓÅÐã°æÖ÷

¡¾´ð°¸¡¿Ó¦Öú»ØÌû

Figure 1 and 2 showed  that 0.6wt¡ë amount of iron existed on the fresh catalyst, which is from the raw materials for catalyst preparation  and  has no negative effect on the hydroisomerization reaction, since it is located in the catalyst support bulk with an inert state. The Fe content after reaction increases remarkably to more than 1.2 wt¡ë as the  2Kh and 8Kh shown  in Figure 1 and 2. At same time , all the Fe species adsorbed during reactions and located  on the catalyst surface are either  reduced or oxidized . These Fe components on the surface  have  a series  of  complicated negative effects on the acidic and metallic sites of the surface , or even plug the catalysts pores  under  long time Fe   enrichment of  reagent oil. Further more, the solid Fe deposits on the catalyst can hardly be removed either  by reductive or oxidative treating method. For this reason, Fe species in the reagent oil  must be removed before reaction.
£¿
3Â¥2014-03-31 22:18:28
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

RXMCDM

°æÖ÷ (ÎÄ̳¾«Ó¢)

ÓÅÐã°æÖ÷ÓÅÐã°æÖ÷ÓÅÐã°æÖ÷

ÒýÓûØÌû:
4Â¥: Originally posted by mac194 at 2014-04-01 09:47:48
Because of the way it's prepared, fresh catalyst is held intact and protected especially on the outside by inert steel.  That outside layer (0.6wt¡ë as shown in Fig's 1 and 2) keeps acidic and meta ...

ÈóɫĿµÄÊÇÒª±ÈÔ­ÎĸüÒ×¶Á,¸üÄÜÎüÒý¶ÁÕß¡£ÎÒµÄÀí½âÊǸÄÕý´íÎó£¬Äܹ»¹µÍ¨¡£with reduced or oxidized statesµÄÒâ˼ÎÒ¹À¼ÆÊÇÒòΪÁ¿¼õÉÙÁË£¬»òÕß±»Ñõ»¯ÁË£¬ËùÒÔ²»²úÉú¸ÉÈÅ¡£support bulk¹À¼ÆÊÇÖ§³Ö²¿·Ö£¬²»ÊǻÖÐÐĵÄÒâ˼¡£·´ÕýÐÞ¸ÄͦÄѵ쬲»ÖªµÀºÏ²»ºÏÇóÖúÕßµÄÒâ˼¡£
£¿
5Â¥2014-04-01 15:03:59
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
×î¾ßÈËÆøÈÈÌûÍÆ¼ö [²é¿´È«²¿] ×÷Õß »Ø/¿´ ×îºó·¢±í
[¿¼ÑÐ] Ò»Ö¾Ô¸ÎäÀí³µÁ¾×¨Ë¶×Ü·Ö 281 Çóµ÷¼Á +3 Éϰ¶Ñо¿Éú. 2026-04-02 3/150 2026-04-06 16:46 by СÔ¶ùѽѽ
[¿¼ÑÐ] Çóµ÷¼Á +10 chenxrlkx 2026-04-05 10/500 2026-04-06 11:31 by Öí»á·É
[¿¼ÑÐ] 319·Ö085702°²È«¹¤³ÌÇóµ÷¼Á +4 rious 2026-04-05 4/200 2026-04-06 11:08 by ¾²¾²¾²¾²¾²¾²¾²¾
[¿¼ÑÐ] Çóµ÷¼Á£¬Ò»Ö¾Ô¸Ö£ÖÝ´óѧ²ÄÁÏÓ뻯¹¤×¨Ë¶£¬Ó¢¶þÊý¶þ342·Ö£¬ÇóÀÏʦÊÕÁô +19 v12abo 2026-04-02 21/1050 2026-04-06 09:29 by À¶ÔÆË¼Óê
[¿¼ÑÐ] Ò»Ö¾Ô¸ ½­ÄÏ´óѧ 085602 »¯¹¤×¨Ë¶ 338·ÖÇóµ÷¼Á +15 ·³ÕСç÷ 2026-04-05 15/750 2026-04-06 09:27 by cql1109
[¿¼ÑÐ] 294Çóµ÷¼Á +4 Grey_Ey 2026-04-01 5/250 2026-04-05 23:05 by Grey_Ey
[¿¼ÑÐ] µ÷¼ÁÇóÖú +10 Ïë»»ÊÖ»ú²»Ïë½âÊ 2026-04-02 13/650 2026-04-05 09:41 by sam3303
[¿¼ÑÐ] 311·Ö 22408 Çóµ÷¼Á +3 bing_bot 2026-04-03 3/150 2026-04-05 00:43 by chongya
[¿¼ÑÐ] ÇóÉúÎïѧѧ˶µ÷¼Á¡ª¡ª364·Ö +7 ÔÆ¶äåÞÍäÖ¸ÄÏ 2026-04-04 7/350 2026-04-04 22:49 by zhyzzh
[¿¼ÑÐ] Ò»Ö¾Ô¸ÉϺ£´óѧÉúÎïѧ346 +3 ÉϺ£´óѧ346µ÷¼Á 2026-04-03 3/150 2026-04-04 20:20 by dongzh2009
[¿¼ÑÐ] Ò»Ö¾Ô¸»¦9£¬ÇóÉúÎïѧµ÷¼Á£¬326·Ö +6 Áõīī 2026-04-04 6/300 2026-04-04 19:44 by ÌÆãå¶ù
[¿¼ÑÐ] 309·Ö085801Çóµ÷¼Á +11 MY_angel 2026-03-31 11/550 2026-04-04 19:11 by À¶ÔÆË¼Óê
[¿¼ÑÐ] 333Çóµ÷¼Á +9 °¢¿ÆÒÝ 2026-03-31 9/450 2026-04-04 18:25 by macy2011
[¿¼ÑÐ] 26µ÷¼Á 086003 +6 ʧ»îµÄϸ°û 2026-04-04 6/300 2026-04-04 09:50 by zhangdingwa
[¿¼ÑÐ] ¿¼Ñе÷¼Á +3 15615482637 2026-04-03 3/150 2026-04-03 22:50 by ms629
[¿¼ÑÐ] Çóµ÷¼Á +8 akdhjs 2026-04-03 8/400 2026-04-03 18:17 by ´÷άING
[¿¼ÑÐ] 338Çóµ÷¼Á +7 êɹ¦? 2026-04-03 7/350 2026-04-03 16:46 by wxiongid
[¿¼ÑÐ] 085600£¬320·ÖÇóµ÷¼Á +6 ´ó²öС×Ó 2026-04-02 6/300 2026-04-02 21:54 by dongzh2009
[¿¼ÑÐ] 354Çóµ÷¼Á +4 lxb598 2026-03-31 5/250 2026-04-02 09:55 by Jaylen.
[¿¼ÑÐ] 349Çóµ÷¼Á +6 ³ÔµÄ²»ÉÙ 2026-04-01 6/300 2026-04-01 17:55 by JYD2011
ÐÅÏ¢Ìáʾ
ÇëÌî´¦ÀíÒâ¼û