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leiwsÖÁ×ðľ³æ (Ö°Òµ×÷¼Ò)
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ÒòΪACSÆÚ¿¯×î½üÕâ¸öÔÂÆµÆµµÄ³öÎÊÌâ...Êý¾ÝÔì¼ÙʲôµÄ...Óлú³öÎÊÌâһƪ£¬ÄÉÃ׳öÎÊÌâһƪ...ACSµÄÏà¹ØÆÚ¿¯Ö÷±àÏÖÔÚ´¦ÓÚÓßÂÛµÄÖÐÐÄ¡« Óлú²¿·Öʼþ»Ø¹Ë£º A recently published ASAP article in the journal Organometallics is sure to raise some eyebrows in the chemical community. While the paper itself is a straightforward study of palladium and platinum bis-sulfoxide complexes, page 12 of the corresponding Supporting Information file contains what appears to be an editorial note that was inadvertently left in the published document: ¡°Emma, please insert NMR data here! where are they? and for this compound, just make up an elemental analysis¡¡± This statement goes beyond a simple embarrassing failure to properly edit the manuscript, as it appears the first author is being instructed to fabricate data. Elemental analyses would be very easy to fabricate, and long-time readers of this blog will recall how fake elemental analyses were pivotal to Bengu Sezen¡¯s campaign of fraud in the work she published from 2002 to 2005 out of Dalibor Sames¡¯ lab at Columbia. The compound labeled 14 (an acac complex) in the main paper does not appear to correspond to compound 14 in the SI. In fact, the bridged-dichloride compound appears to be listed an as unlabeled intermediate in Scheme 5, which should raise more eyebrows. Did the authors unlist the compound in order to avoid having to provide robust characterization for it? ÄÉÃ×ÔÌû³ö´¦£º http://www.chemistry-blog.com/20 ... om-the-pease-group/ ÓлúÔì¼ÙÎļþ³ö´¦£º http://blog.chembark.com/2013/08 ... t-si-file/#comments ¸öÈ˾õµÃ£º ÄÉÃ×µÄÄǸçÃÇPSµÄͼ±È½Ï¿É°®...»¹´øÒõÓ°µÄ Óлú²¿·ÖµÄ»Ø¸´ÁÁϹÁË...ÓÈÆäÊÇÄǾ䡰make up¡±... Ò»ÆðÀ´Ì¸Ì¸ÄÇЩÄêÎÒÃǼû¹ýµÄ¸÷ʽ¸÷ÑùµÄÂÛÎÄÎè±×ÐÐΪ¡«¡«¡« [ Last edited by leiws on 2013-8-21 at 15:57 ] |
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metalmood
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2Â¥2013-08-21 17:31:59
mapenggao
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3Â¥2013-08-24 22:57:08













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