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Although the flexibility around the etheric O atom leads to the formation of a 1D helical chain structure, the entire 3D architecture of complex 4 is achiral owing to the phenomenon that the left-handed screws (L-helix) and the right-handed ones (R-helix) arrange alternatively in the ac plane linked by C¨CH ¡¤¡¤¡¤O hydrogen bonding interactions between the C10 atom from the phen ligand and O1W from the coordinated water molecules with a C ¡¤¡¤¡¤O distance of 3.060(6) A˚ |
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2Â¥2013-05-16 22:15:11
LJ-qiuwei
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3Â¥2013-05-17 06:51:05
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½ð³æ (ÕýʽдÊÖ)
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- ½ð±Ò: 3136.5
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- ºì»¨: 11
- Ìû×Ó: 464
- ÔÚÏß: 117.7Сʱ
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LJ-qiuwei: ½ð±Ò+10, ·ÒëEPI+1, ¡ïÓаïÖú 2013-05-18 07:35:12
LJ-qiuwei: ½ð±Ò+10, ·ÒëEPI+1, ¡ïÓаïÖú 2013-05-18 07:35:12
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