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¡°Tb(hfa)3diglyPU¡± polyurethane compositewas prepared from the complex solution in polyol (22 mmol/l), which was mixed with hexamethylenediisocyanate (1:1 ratio), after vacuum removal of air bubbles, the polymerization was carried out at 60 ◦C. Composites with Eu(ttfa)3phen were obtained analogously (a 0.5 mmol/l polyol solution of complex was used). (b) Vacuum dried complexes (2 mmol) were dissolved in dimethylformamide and added to the hexamethylenediisocyanate (1 g, ratio ¨COH:NCO or ¨CNH2:NCO approximately 1:100), dimethylformamide was evaporated in vacuum and the complex solution in diisocyanate thus obtained was mixed with the polyol (1:1 ratio), air bubbles were removed under vacuum. The polymerization to give the polyurethane was again carried out at 60 ◦C. The emission intensities (not quantum yields) were at a maximum at approximately 10−2 mol complex/L. Çó·ÒëÕâÁ½¶Î»° |
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shmily11125: ½ð±Ò+5, ·ÒëEPI+1 2013-05-27 09:32:22
shmily11125: ½ð±Ò+5, ·ÒëEPI+1 2013-05-27 09:32:22
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4Â¥2013-05-26 16:17:17
shmily11125
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5Â¥2013-05-27 09:32:11
shmily11125
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6Â¥2013-05-27 09:32:31














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