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Title: STUDIES ON THE TRANSFORMATION FROM AN INTERMEDIATE ALUMINOPHOSPHATE PHASE TO THREE-DIMENSIONAL OPEN-FRAMEWORKS Source: HYDROTHERMAL REACTIONS AND TECHNIQUES Author(s): CAIJIN LI State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China, China JIHONG YU State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China, China KAIXUE WANG State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China, China LI PENG State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China, China RUREN XU State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China, China Abstract: An intermediate aluminophosphate phase [Al2P2O8(OH)2]¡¤2[HOCH2CH2NH3], denoted as APO-M, is isolated in a pure form during the crystallization of a three-dimensional open-framework APO-CJ3, and characterized by XRD, TG-DTA, MAS NMR, ICP and CHN analyses. Our studies show that APO-M can transform to APO-CJ3, as well as to AlPO4-21 under hydrothermal treatment. The phase transformation process has been further studied. It is believed that the phase transformation from APO-M to AlPO4-21 is via a solid-to-solid conversion process, which has been confirmed by the dry-crystal conversion experiment. Full Text: View full text in PDF format TOC: Back to Table of Contents ²»ÖªÄÄλ¿ÉÒÔ¹²Ïí£¿ |
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ÕâÖ»ÊÇÒ»±¾ÊéµÄÒ»²¿·Ö£¬ÊéµÄÏà¹ØÐÅÏ¢ÈçÏ¡ª¡ª HYDROTHERMAL REACTIONS AND TECHNIQUES Proceedings of the Seventh International Symposium on Hydrothermal Reactions Changchun, China 14 - 18 December 2003 edited by S H Feng, J S Chen & Z Shi (Jilin University, P R China) Hydrothermal techniques have been widely used in the synthesis of advanced materials, the treatment of wastes, and the preparation and extraction of special chemicals. They have also been studied for the mimicking of geothermal processes. Nowadays, hydrothermal techniques and sciences play a very important role both in industry and in academia. This book includes contributions from chemists and chemical engineering scientists worldwide who are active in the field of hydrothermal reactions and techniques. The topics covered range from fundamentals of hydrothermal reactions, modeling of hydrothermal processes, new techniques for hydrothermal treatment, and new materials from hydrothermal systems to supercritical fluid reaction systems. Contents: Hydrothermal and Solvothermal Chemistry Supercritical Fluids, Supercritical Water Oxidation Process and Waste Treatment Growth of Single Crystals, Thin Films, Nanomaterials and Oriented Organization Inorganic£organic Hybrid Materials New Techniques, Theory and Modeling Readership: Graduate students, academics and researchers in industrial chemistry, inorganic chemistry, physical chemistry, chemical engineering and materials science. 552pp Pub. date: Nov 2003 ISBN 981-238-675-0 US$145 / £107 Google ¿ÉÒÔä¯ÀÀµÄÒ³ÃæÈçÏ¡ª¡ª http://books.google.com/books?hl ... AcHZiea6rYmHE#PPA12,M1 |
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