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Pure Appl. Chem., Vol. 73, No. 3, pp. 469–474, 2001.
© 2001 IUPAC
469
Electron-transfer dyads suitable for novel
self-assembled light-harvesting antenna/
electron-transfer devices*
Alfred R. Holzwarth†, Martin Katterle, Marc G. Müller, Ying-Zong Ma,
and Valentin Prokhorenko
Max-Planck-Institut für Strahlenchemie, Stiftstraße 34-36, 45470 Mülheim/Ruhr,
Germany
Abstract: The synthesis and photophysical and photochemical characterization of four novel
bacterio-chlorin-fullerene dyads with fullerene C60 coupled at various positions and by various
bridges to the chlorin ring are described. All dyads undergo rapid charge separation in
the sub-picosecond to picosecond time range as characterized by time-resolved fluorescence
and transient absorption spectroscopy.
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