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小金鱼lv

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HCPTP再镍Ni钴Co反应生成配合物[Ni(CPTP)2-(C2H5OH)2](C2H5OH) [Co (CPTP)2-(C2H5OH)2](C2H5OH),然后对所得产物结构采用红外和紫外进行了 初步表征。研究发现这两种配合物的红外光谱都在3010 cm-1弱 的吸收峰,归属于酮的互变异构体中羟基的振动吸收,在1610-1450cm-1有强的吸收峰,归属于苯环碳骨架伸缩振动的特征峰;在1585 cm-1处存在C=N的振动吸收; 在1250 cm-1 1500 cm-1 1523 cm-1 均有吸收,在1430 cm-1有较强的吸收,归属于噻吩环的特征吸收;在1559 cm-1处是羰基氧与金属离子发生配位后的C-O键的特征吸收;在260-258 nm处的吸收是氧与金属配位键的特征吸收。
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爱与雨下: 金币+1 2012-06-16 21:45:35
sltmac: 违规存档, 机器翻译,已数次犯,在本版禁言 2012-06-26 08:19:33
HCPTP then Nickel Ni Cobalt Co. produced by the reaction with the matter of [Ni (CPTP) 2 - (C2H5OH) 2] (C2H5OH) [Co (CPTP) 2 - (C2H5OH) 2] (C2H5OH), then the income structure of the product by infrared and ultravioletconducted a preliminary characterization. Study found that the infrared spectra of these two complexes are in the weak 3010 cm - 1 absorption peak attributable to the ketone tautomer of hydroxyl groups vibration absorption, the strong absorption peak at 1610-1450cm-1, attributable to benzene ring carbon skeleton stretching vibration peaks; existence of the C = N vibration at 1585 cm - 1 absorption; 1250 cm - 1 1500 cm-1 1 523 cm-1 have absorption in 1430 cm - 1 absorption attributable to the characteristics of the thiophene ring absorption; carbonyl oxygen and metal ion coordination of the CO bond absorption at 1559 cm - 1; absorption in the 260-258 nm absorption of oxygen and metal coordination bonds .
不是哥不笑,一笑粉就掉
2楼2012-06-10 21:45:27
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