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In general, methodologies based on the use of a stoichio- metric amount of copper are not treated and only synthetic procedures where copper catalysis is involved in the indole or benzofuran ring construction event are discussed herein. Even copper-catalyzed procedures producing indole or benzofuran related compounds such as indolines, oxindoles, indazoles, benzo- furanones, and related systems are not treated and neither are the reactions in which copper catalysis is involved in the cyclization to condensed polycyclic compounds such as pyrazoleindoles, ben- zofuro heterocycles, and related systems discussed. The literature has been surveyed up to the end of 2009. |
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