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roddick8101

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The paper is well-organized and varied characterization techniques have been employed to study the corrosion process of tinplate in functional beverage. Therefore, it has made a significant contribution to understand the corrosion behavior of tinplate in functional beverage. There are a few minor issues that could be addressed to improve the understanding of the paper. Following is the list of those issues:
(1) In Experimental Section, the authors mentioned the crystal structure was identified using an X-ray diffractometer (RIGA- KU/DMAX2500, Japan) (in Line 14-15). However, no results or discussions about XRD were presented in the paper. The analysis from XRD helps to further identify the structures of the corrosion products of tin or Fe compounds. Please add the analysis from XRD in the paper.
(2) A typical three-electrode method was used in EIS testing in this paper. Why was a commercial titanium oxide electrode used as the counter electrode (CE)? (in Line 26 in the paper) Titania is a kind of semiconductor, not as good as the conventional Pt electrode.
(3) The surface structure of the tinplate may change with the increasing immersion time. Part of the corrosion product film detached from the surface when the immersion time was after 31 hours and two layers of corrosion product films were observed in Fig. 5(b) in the paper. Do the authors still think only one constant time occurred in the Bode diagram at that moment? If not, the difference should be discussed more in detail.
(4) Why did the authors select an acid functional beverage as the medium? The authors need address the effect of the acid medium on the corrosion mechanism of the tinplate. Thus, the proposed conclusions seem more instructive and convincing.

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luyuan0920

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roddick8101

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3Â¥: Originally posted by luyuan0920 at 2011-10-26 12:00:47:
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keen

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roddick8101

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5Â¥: Originally posted by keen at 2011-10-26 16:05:02:
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zhuzhuyaya

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nono2009

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