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ËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥±íÃæ»îÐÔ¼ÁµÄºÏ³É¼°ÐÔÄÜ̽ÌÖ Õª Òª ÒÔËÉÏã(RO)ΪÖ÷ÒªÔÁÏ£¬Ñõ»¯Ð¿Îª´ß»¯¼Á£¬Óë¾ÛÒÒ¶þ´¼6000(PEG6000)·´Ó¦ºÏ³ÉÖмäÌåËÉÏã¾ÛÒÒ¶þ´¼õ¥(RPGE)£¬RPGEÔÙÓëÄûÃÊËáºÏ³ÉÒ»ÖÖÐÂÐͱíÃæ»îÐÔ¼ÁËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥£¨RPGCE£©¡£Ì½ÌÖÁ˸ñíÃæ»îÐÔ¼ÁµÄºÏ³ÉµÄ×î¼ÑÌõ¼þ£¬RPGEµÄºÏ³É×î¼ÑÌõ¼þΪ£ºROÓëPEG6000µÄÎïÖʵÄÁ¿Ö®±ÈΪ1¡Ã1. 6£¬·´Ó¦Î¶È270¡æ£¬·´Ó¦Ê±¼ä3h; RPGCEºÏ³ÉµÄ×î¼ÑÌõ¼þΪ:·´Ó¦Î¶È150¡æ, ·´Ó¦Ê±¼ä2.5h¡£Ì½ÌÖÁ˸ñíÃæ»îÐÔ¼ÁµÄ±íÃæÕÅÁ¦(¦Ã),ÁÙ½ç½ºÊøÅ¨¶È(CMC) ,È黯ÐÔ,ÅÝÄÐԵȡ£½á¹û±íÃ÷,RPGEºÍRPGCE¾ùΪÐÔÄÜÓÅÁ¼µÄÐÂÐÍ·ÇÀë×Ó±íÃæ»îÐÔ¼Á¡£ ¹Ø¼ü´Ê:ËÉÏ㣻·ÇÀë×Ó±íÃæ»îÐÔ¼Á£»ËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥£»ºÏ³É£»ÐÔÄÜ¡£ ABSTRACT Study on the Synthesis and Property of the Surfactant Rosin-Polyethylene Glycol-Citric Acid Ester Zinc oxide being catalyst, the main raw material rosin(RO) and PEG6000 are catalyzed to form an intermediates, polyethylene glycol ester of rosin(RPGE), which then reacts with citric acid, leading to formation of a new type of surfactant, rosin-polyethylene glycol-citric acid ester (RPGCE). Discussion on the best conditions for the synthesis of surfactants, the best conditions for synthesis of RPGE : RO and the ratio of amount of substance of PEG6000 to 1:1. 6, the reaction temperature is 270 ¡æ, response time is 3h; Best conditions for the synthesis of RPGCE: reaction temperature 150 ¡æ, response time 2.5h. Discusse the surface tension of surfactant (¦Ã), the critical micelle concentration (CMC), emulsion, foam and so on. Results indicate that both intermediates and objective products are new type of nonionic surfactant with excellent performance . Key words£ºrosin ; nonionic surfactant ; rosin-polyethylene glycol-citric acid ester ; synthesis; property |
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zerohead
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sltmac(½ð±Ò+2): »¶Ó³£À´~~ 2011-05-13 08:46:12
sltmac(½ð±Ò+2): »¶Ó³£À´~~ 2011-05-13 08:46:12
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ÕªÒªÓ¦ÒÔÑо¿Öص㿪¾ä£º ÒÔËÉÏã(RO)ΪÖ÷ÒªÔÁÏ£¬Ñõ»¯Ð¿Îª´ß»¯¼Á£¬Óë¾ÛÒÒ¶þ´¼6000(PEG6000)·´Ó¦ºÏ³ÉÖмäÌåËÉÏã¾ÛÒÒ¶þ´¼õ¥(RPGE)£¬RPGEÔÙÓëÄûÃÊËáºÏ³ÉÒ»ÖÖÐÂÐͱíÃæ»îÐÔ¼ÁËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥£¨RPGCE£©¡£ A new type of surfactant, rosin-polyethylene glycol-citric acid ester (RPGCE), is developed by reacting citric acid with polyethylene glycol ester of rosin (RPGE), an intermediate of the reaction between rosin(RO) and PEG6000 catalyzed by Zinc oxide. |
2Â¥2011-05-07 00:31:52
yinjuanchen
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sltmac(½ð±Ò+3, ·ÒëEPI+1): лл½»Á÷£¬»¶Ó³£À´~~ 2011-05-13 08:46:25
sltmac(½ð±Ò+3, ·ÒëEPI+1): лл½»Á÷£¬»¶Ó³£À´~~ 2011-05-13 08:46:25
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ËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥±íÃæ»îÐÔ¼ÁµÄºÏ³É¼°ÐÔÄÜ̽ÌÖ Õª Òª ÒÔËÉÏã(RO)ΪÖ÷ÒªÔÁÏ£¬Ñõ»¯Ð¿Îª´ß»¯¼Á£¬Óë¾ÛÒÒ¶þ´¼6000(PEG6000)·´Ó¦ºÏ³ÉÖмäÌåËÉÏã¾ÛÒÒ¶þ´¼õ¥(RPGE)£¬RPGEÔÙÓëÄûÃÊËáºÏ³ÉÒ»ÖÖÐÂÐͱíÃæ»îÐÔ¼ÁËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥£¨RPGCE£©¡£Ì½ÌÖÁ˸ñíÃæ»îÐÔ¼ÁµÄºÏ³ÉµÄ×î¼ÑÌõ¼þ£¬RPGEµÄºÏ³É×î¼ÑÌõ¼þΪ£ºROÓëPEG6000µÄÎïÖʵÄÁ¿Ö®±ÈΪ1¡Ã1. 6£¬·´Ó¦Î¶È270¡æ£¬·´Ó¦Ê±¼ä3h; RPGCEºÏ³ÉµÄ×î¼ÑÌõ¼þΪ:·´Ó¦Î¶È150¡æ, ·´Ó¦Ê±¼ä2.5h¡£Ì½ÌÖÁ˸ñíÃæ»îÐÔ¼ÁµÄ±íÃæÕÅÁ¦(¦Ã),ÁÙ½ç½ºÊøÅ¨¶È(CMC) ,È黯ÐÔ,ÅÝÄÐԵȡ£½á¹û±íÃ÷,RPGEºÍRPGCE¾ùΪÐÔÄÜÓÅÁ¼µÄÐÂÐÍ·ÇÀë×Ó±íÃæ»îÐÔ¼Á¡£ ¹Ø¼ü´Ê:ËÉÏ㣻·ÇÀë×Ó±íÃæ»îÐÔ¼Á£»ËÉÏã¾ÛÒÒ¶þ´¼ÄûÃÊËáõ¥£»ºÏ³É£»ÐÔÄÜ¡£ ABSTRACT The Synthesis and Property Study of the Surfactant Rosin-Polyethylene Glycol-Citric Acid Ester Polyethylene glycol ester of rosin(RPGE) is produced by the reaction between themain raw material rosin(RO) and PEG6000 with zinc oxide catalysis . It reacts with citric acid, leading to formation of a new type of surfactant, rosin-polyethylene glycol-citric acid ester (RPGCE). The best conditions to synthesis the two surfactants were discussed. The condition for RPGE is that the reaction of RO and PEG6000 is controlled for 3h at 270 ¡æ, with the ratio of amount of substanceo 1:1. 6, and the reaction time can be controlled for 2.5h at 150 ¡æ for RPGCE . The surface tension of surfactant (¦Ã), the critical micelle concentration (CMC), emulsion, foam,ect were also discussed . Results indicate that both intermediates and objective products are new type of nonionic surfactants with excellent performance . Key words£ºrosin ; nonionic surfactant ; rosin-polyethylene glycol-citric acid ester ; synthesis; property ¾¡Á¿Ê¹Óñ»¶¯Óï̬£¬ÁíÍâÎÒ¾õµÃÄãµÄÌâÄ¿·ÒëµÄ²»ÊǺÜÍ×£¬ÉÔ×÷ÐÞ¸ÄÁË£¬Ï£ÍûÓаïÖú¡£ |

3Â¥2011-05-08 08:21:23














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