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authors correctly report that all the efficient channels lie below reactant energies. It means that, according to the gas phase experiment carried out at relatively low pressure and with very high reaction coefficients, all these reactions take place at constant energy and angular momentum. Therefore many (I would say all) of the observed branching ratios plausibly derive from dynamical effects which may drastically deviate from the zero-kelvin (zero-momentum) conditions outlined by authors. Therefore they should report a brief comment about the actual (although not sever) limitations in the comparison of their results with the experimental ones. In other words I would be a bit more careful in describing the apparent discrepancy of PC-PE relative efficiency as a result of problems in the experiments.......
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Therefore they should report a brief comment about the actual (although not sever) limitations in the comparison of their results with the experimental ones.
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Therefore many (I would say all) of the observed branching ratios plausibly derive from dynamical effects which may drastically deviate from the zero-kelvin (zero-momentum) conditions outlined by authors.
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boylc789

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32587305(½ð±Ò+5):лл£¬ÖÕÓÚŪÃ÷°×ÁË¡£ 2011-01-04 16:57:15
32587305(½ð±Ò+1): 2011-04-25 22:20:19
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Originally posted by boylc789 at 2010-12-28 22:55:08:

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boylc789

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32587305(½ð±Ò+2):ÎÒ´óÖÂÀí½âÊÇÕâ¸öÒâ˼£¬Ö»ÊDz»ÖªµÀÁ㿪¶ûÎÄ·ÅÔÚÕâÀïÊÇʲôÒâ˼¡£ÀíÂÛºÍʵÑ鶼ûÓÐÓõ½°¡¡£ 2010-12-29 11:22:11
32587305(½ð±Ò+1): 2011-04-25 22:20:12
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Originally posted by 32587305 at 2010-12-28 18:15:43:
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authors correctly report that all the efficient channels lie below reactant energies. It means that, according to the gas phase ...

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tiechong

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