| 查看: 2442 | 回复: 3 | |||
| 本帖产生 1 个 翻译EPI ，点击这里进行查看 | |||
[交流]
重金求化学合成翻译，高手进来指导指导
|
|||
|
To a flame-dried Schlenk test tube with a magnetic stirring bar was charged CuI (38.2 mg, 0.2 mmol), Cs 2 CO 3 (0.65 g, 2.0 mmol), nitrogen- containing heterocycle (1.4 mmol), aryl or heteroaryl halide (1.0 mmol), and DMF (2 mL) under N 2 . A rubber septum was replaced with a glass stopper, and the system was then evacuated twice and back filled with N 2 . The reaction mixture was stirred for 30 min at room temperature, and then heated at 120 °C for 40 h. The reaction mixture was then cooled to ambient temperature, diluted with 2-3 mL of ethyl acetate, filtered through a plug of silica gel, and washed with 10-20 mL of ethyl acetate. The combined organic extracts were concentrated, and the resulting residue was purified by column chromatography on silica gel to provide the desired product. 以上是一段合成的步骤，filtered through a plug of silica gel, and washed with 10-20 mL of ethyl acetate. The combined organic extracts were concentrated,这一段非常的难懂啊，高手们进来看看，指导指导啊 |
回复此楼» 猜你喜欢
国自然面上复盘~欢迎讨论
已经有6人回复
-
售SCI一区文章，我:8.O.551.O.5.4,科目全,可伽急
已经有4人回复
-
有多少人是今天查系统知道结果的？
已经有17人回复
-
售SCI一区T0P文章，我:8.O.55.1.O.54,科目齐全,可+急
已经有4人回复
-
基金不中，共勉
已经有5人回复
-
看板上这么多中的，有点像50人群里49个人都是骗子的那种感觉……
已经有3人回复
-
我不理解！
已经有23人回复
-
2026年的国家社科基金项目通讯评审的新规则与新动向、新挑战
已经有10人回复
-
系统查不到
已经有10人回复
-
怎么查啊
已经有5人回复
cfk580713
至尊木虫 (著名写手)
- 翻译EPI: 277
- 应助: 30 (小学生)
- 贵宾: 0.038
- 金币: 13606.7
- 散金: 123
- 红花: 6
- 帖子: 1261
- 在线: 829.2小时
- 虫号: 253096
- 注册: 2006-05-20
- 性别: GG
- 专业: 有机高分子功能材料
2楼2010-09-20 16:16:33
slowstar
木虫 (职业作家)
- 翻译EPI: 13
- 应助: 12 (小学生)
- 金币: 16725.5
- 红花: 2
- 帖子: 3384
- 在线: 803.3小时
- 虫号: 712881
- 注册: 2009-03-02
- 性别: GG
- 专业: 热力学
★ ★ ★ ★ ★ ★ ★ ★
发芽土豆(金币+2):谢谢参与 2010-09-23 09:46:24
baishitou3(金币+5): 2010-09-27 08:40:33
baishitou3(金币+2): 2010-10-04 22:06:17
ringzhu(金币+6): 2010-11-22 12:32:07
发芽土豆(金币+2):谢谢参与 2010-09-23 09:46:24
baishitou3(金币+5): 2010-09-27 08:40:33
baishitou3(金币+2): 2010-10-04 22:06:17
ringzhu(金币+6): 2010-11-22 12:32:07
|
filtered through a plug of silica gel, and washed with 10-20 mL of ethyl acetate. The combined organic extracts were concentrated, and the resulting residue was purified by column chromatography on silica gel to provide the desired product. （在砂心漏斗或布氏漏斗里）先填上些硅胶，然后抽滤，再用10-20 mL乙酸乙酯淋洗。合并所得滤液（即抽滤和乙酸乙酯淋洗所得的滤液），将滤液浓缩（用旋转蒸发仪最方便了）后所得的剩余物过硅胶柱（即有机合成上俗称的过柱子），即可得到所需产物。 |
3楼2010-09-20 22:21:45
slowstar
木虫 (职业作家)
- 翻译EPI: 13
- 应助: 12 (小学生)
- 金币: 16725.5
- 红花: 2
- 帖子: 3384
- 在线: 803.3小时
- 虫号: 712881
- 注册: 2009-03-02
- 性别: GG
- 专业: 热力学
4楼2010-09-20 22:23:19
