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层内脱水时，纳米管受轴向力，管形貌能够保持稳定，层间脱水时纳米管受径向力，因而会塌陷断裂。 与层间脱水形成Ti-O键同步，在纳米管内硝酸镍分解，集聚形成Ni0颗粒，当其直径达到与纳米管内径接近时，就会产生一个支撑力，抵消挤压的应力，避免塌陷发生 ， [ Last edited by wolfmanhd on 2010-7-5 at 15:09 ] |
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wypward(金币+1):谢谢参与 2010-07-05 18:41:53
wolfmanhd(金币+10, 翻译EPI+1):翻译的不错，谢谢了 2010-07-05 18:44:30
wypward(金币+1):谢谢参与 2010-07-05 18:41:53
wolfmanhd(金币+10, 翻译EPI+1):翻译的不错，谢谢了 2010-07-05 18:44:30
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When dehydration occured in layers, the nanotubes was under axial force, the tube shape can remain stable.When dehydration occured between layers, the nanotubes was under radial force, thus they will collapse to fracture. Ni(N03)3 decomposed in the nanotubes when Ti-O bond was formed in dehydration between layers, then NiO was formed by accumulation. If the diameter of NiO increased closely to that of the nanotubes, it will bring about a support force to offset compression stress so as to avoid the collapse. |
2楼2010-07-05 18:01:48