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sd71469190

木虫 (著名写手)

应助: 8 (幼儿园)
金币: 3200.1
散金: 72
红花: 7
帖子: 1030
在线: 304.3小时
虫号: 110958
注册: 2005-11-20
性别: GG
专业: 配位化学

[交流] CryEngComm小修，大家都是多久回复的。（附有审稿意见）已有9人参与

Reviewer(s)' Comments to Author:
Referee: 1
Comments to the Author
The present manuscript (CrystEngComm CE-ART-××××××) by×××× et al. is an interesting piece of work that deals with the synthesis and detailed description of X-ray crystal structures of the two coordination polymers. The thermal and photoluminescent properties of the obtained materials have been also studied. The work appears to be rather original, the methodology is appropriate and the conclusions made correspond to the obtained results. The graphical material is rather appealing and facilitates the understanding of structural features. In general, this work is lies within the scope of CrystEngComm, and its acceptance can be recommended after the minor revision, which should address the following points.

1. The main criticism concerns some hidden details in the synthetic procedure for compounds 1 and 2. These parameters are very important for the reproducibility of the syntheses and must be clearly described.－－－好解决
2. Providing that the compounds have been only characterized by IR-spectroscopy, X-ray structural and elemental analyses, all the bands in the IR-spectra should be specified in section 2.2. In addition, the IR spectra should be given in supporting information.－－－好解决，但是要指认全部红外的峰太难了
3. Graphical abstract and synopsis are missing.－－－好解决
4. The manuscript contains a number of unclear/incorrect expressions (or typos) that should be corrected (e.g. p. 1, line 28; p. 1, lines 32-36; p. 3, lines 2-3; p. 3, line 21; p. 7; line 3, etc.).
－－－好解决

Referee: 2
Comments to the Author
The paper of ××× reports interesting coordination system and it is interesting for many reasons, which are associated with the original coordination geometries and topology of the compounds. The paper perfectly matches the area of the Journal. It describes a reasonable number of new crystal structures together with a very proficient presentation and discussion. I am happy to support this publication after a certain revision concerning analysis of interpenetration in the crystal structures and somewhat more intensive chemical discussion.

1 The authors should analyze the terminology and symbology of interpenetration according to the most recent works. See:
V.A. Blatov, et al., "Vertex-, face-, point-, Schlfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology" CrystEngComm, 2009, 12, 44-48.
I.A. Baburin, et al., Interpenetrated Three-Dimensional Networks of Hydrogen-Bonded Organic Species: A Systematic Analysis of the Cambridge Structural Database, Cryst. Growth Des.; 2008; 8(2); 519-539.
I.A. Baburin, et al., Interpenetrated three-dimensional hydrogen-bonded networks from metal-organic molecular and one- or two-dimensional polymeric motifs
CrystEngComm, 2008, 10, 1822-1838
关于拓扑分析，我的结构是比较简单的44格子的穿插，这样子让分析拓扑好像很棘手
2 Also, considering very subtle functional features of the coordinated aminopyrimidine ligand, it may be important to find more discussion for the role of amino group. Thus, the silver ion coordinating to the pyrimidine N-site together with the adjacent NH2 it total constitute a multiple site for the binding of counter anions or solvate H-bond donating/accepting molecules, which may a special feature of the present system or even its special benefit. Additional short discussion for the related complexes with such N/NH-donating species ( could be very helpful.
－－－好解决

大家都积极回复阿，看看这种情况需要修改后几天回复阿，我其实已经修改完毕了，文章又看了3遍了（不是一天看的）。这种中的几率如何？没太大信心阿

[ Last edited by lby1258 on 2010-6-4 at 20:55 ]

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