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jsyhn

ľ³æ (СÓÐÃûÆø)

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ͨ¹ý±È½ÏÄÉÃ×Ñõ»¯Í­ (CuO NPs), ΢Ã×Ñõ»¯Í­ (CuO MPs)ÔÚÁ½ÖÖÍÁÈÀÖеÄCu2+Èܳö¼°Æä¶Ôëåø»îÐÔÓ°Ïì, ½áºÏ¿É²úÉúëåø»îÐÔÒÖÖÆÐ§Ó¦µÄCu2+Ũ¶ÈãÐÖµ, Ñо¿ÁËCuO NPsºÍCuO MPs¶ÔÍÁÈÀëåø»îÐԵ;ÐÔЧӦ»úÖÆ. ½á¹û±íÃ÷: CuO NPsºÍCuO MPsµÄCu2+ÈܳöÁ¿ËæÆäŨ¶ÈÔö¼Ó¶øÔö¼Ó, Èܳö±ÈÂÊËæÅ¨¶ÈÔö¼Ó¶ø¼õÉÙ, Á½ÕßÔÚºìÈÀÖеÄCu2+Èܳö¾ù¸ßÓÚÆäÔÚÎÚÕ¤ÍÁÖУ»ÔÚ1¡«100 mg • kg-1·¶Î§ÄÚ, CuO NPs¶ÔÍÁÈÀëåø»îÐÔ²úÉúÁËÏÔÖø£¨p ¡Ü0.05£©»ò¼«ÏÔÖø£¨p ¡Ü0.01£©µÄÒÖÖÆÐ§Ó¦, ͬŨ¶ÈÏÂ, CuO NPsÔÚÍÁÈÀÖеÄCu2+Èܳö¼°Æä¶Ôëåø»îÐÔµÄÒÖÖÆÐ§Ó¦¾ù´óÓÚCuO MPs; ÔÚÏà¶ÔµÍŨ¶È (1¡«10 mg • kg-1, ºìÈÀ; 1¡«100 mg • kg-1, ÎÚÕ¤ÍÁ)ÏÂ, ÄÉÃ׿ÅÁ£Ì¬µ¼ÖÂÁËCuO NPs¶ÔÍÁÈÀëåø»îÐÔµÄÒÖÖÆ¶¾ÐÔ, ÔÚÏà¶Ô¸ßŨ¶È (¡Ý50 mg • kg-1, ºìÈÀ; ¡Ý500 mg • kg-1, ÎÚÕ¤ÍÁ)ÏÂ, ÄÉÃ׿ÅÁ£Ì¬ºÍÈܳöCu2+¹²Í¬×÷ÓÃÒýÆðÁËëåø»îÐÔÒÖÖÆ£»ÓëCuO NPs ²»Í¬, CuO MPsÖ»ÓÐͨ¹ýÈܳöCu2+ÒÖÖÆÍÁÈÀëåø»îÐÔ, Æä¿ÅÁ£Ì¬¶Ôëåø»îÐÔÎÞÏÔÖøÓ°Ïì; ÖµµÃ×¢ÒâµÄÊÇ, ÔÚµÍŨ¶È(1 mg • kg-1)ÏÂCuO NPs¶ÔÍÁÈÀëåø»îÐÔ¾ßÓÐ΢Ã×̬ºÍÀë×Ó̬ËùûÓеÄÒÖÖÆ¶¾ÐÔ, ˵Ã÷Æä¶ÔÍÁÈÀøӰÏìÓ¦´æÔÚÌØÊâ»úÀí, ÖµµÃ½øÒ»²½ÉîÈëÑо¿.

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ëåø£ºurease »îÐÔ£ºactivity Èܳö£ºrelease  ÒÖÖÆ£ºinhibit/inhibition  ºìÈÀ£ºUdic Ferrosols
ÎÚÕ¤ÍÁ£ºAnthrosol

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СÓÍ2716

ľ³æ (ÕýʽдÊÖ)

jsyhn(½ð±Ò+20, ·­ÒëEPI+1):ÐÁ¿àÁË£¬µ«ÄãºÃÏñÊÇÖ±ÒëµÄ£¬ÕâÑù»¹ÊDz»ÐУ¬²»ºÃÒâ˼£¬±í±íÐÄÒ⣬ʣϵĵȴý×îÓÅ·­ÒëÁË 2010-05-09 23:33:20
By comparing the Cu2+ release and the effects of urease's activity of  CuO NPs and CuO MPs in two kinds of soil,combining the threshold concentration of Cu2+ which can have inhibiting action to urease's activity,we studied the mechanism of the toxic effects to soil urease's activity given by CuO NPs and CuO MPs.It showed that the Cu2+ release of CuO NPs and CuO MPs enhanced by the increasng of their concentrations, the dissolving rate was to the contrary.Both of their  Cu2+ release are higher in Udic Ferrosols than Anthrosol .In the range of 1 to 100 mg • kg-1,CuO NPs had a prominent inhibiting action to urease with p ¡Ü0.05 and highly significant action with p ¡Ü0.01.In the same concentration,the Cu2+ release and the effects of urease's activity of  CuO NPs was over to CuO MPs.In the relatively low concentration(1¡«10 mg • kg-1 in Udic Ferrosols and Anthrosol),the nanoparticle form resulted the inhibitorytoxicity of CuO NPs to urease's activity.In the relatively high concentration((¡Ý50 mg • kg-1 in Udic Ferrosols,¡Ý500 mg • kg-1 in Anthrosol),the synergy of nanoparticle form and  Cu2+ release produced  inhibiting action to urease's activity.Differing to CuO NPs,CuO MPs  inhibited the activity of urease only through Cu2+ release,its nanoparticle form didn't have a remarkable influence.It's wroth to learn,CuO NPs had a inhibitorytoxicity in the low concentration(1 mg • kg-1) which
the submicronin form and ionic form didn't have. That showed that there was a special mechanism for the influence of CuO NPs to soil enzyme taht's wroth to do a deep study.²»ÖªµÀÄܲ»ÄܰﵽÄã
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2Â¥2010-05-09 22:44:58
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

mmyytiger

ÖÁ×ðľ³æ (Ö°Òµ×÷¼Ò)

Ժʿ

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wypward(½ð±Ò+30): 2010-05-21 19:31:58
By comparing the nano-copper oxide (CuO NPs), micron copper oxide (CuO MPs) in two soil Cu2 + dissolution and its urease activity, combined to produce urease activity inhibition effect of the Cu2 + concentration threshold of the CuO NPs and CuO MPs on soil urease activity of the toxic effect mechanism. The results show that: CuO NPs and CuO MPs of Cu2 + dissolution increased with its concentration increases, dissolution rate with the concentration decreased, both in the red in the Cu2 + dissolution was higher than its In Wushan soil; in 1 ~ 100 mg • kg-1 range, CuO NPs on soil urease activity produced a significant (p ¡Ü 0.05) or highly significant (p ¡Ü 0.01) inhibitory effect, the same concentration, CuO NPs Cu2 + in the soil dissolution and on the inhibitory effect of urease activity was higher than CuO MPs; in relatively low concentrations (1 ~ 10 mg • kg-1, red; 1 ~ 100 mg • kg-1, Wushan soil) under nano-particle states leads to CuO NPs on urease activity inhibition of toxicity, a relatively high concentration (¡Ý 50 mg • kg-1, red; ¡Ý 500 mg • kg-1, Wushan soil), the nano-particulate and dissolved Cu2 + interaction caused urease activity inhibition; and CuO NPs different, CuO MPs only through the dissolution of Cu2 + inhibition of urease activity, the particulate on urease activity had no significant effect; It is noteworthy that, in low concentration (1 mg • kg-1 ) under the CuO NPs on soil urease activity states and ionic states with micron not inhibited by the toxicity, indicating its impact on soil enzyme should exist a special mechanism, it is worth further study.
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3Â¥2010-05-14 19:31:14
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