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dangqq1982

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Reviewer(s)' Comments to Author:
>Reviewer: 1
>
>Recommendation: Publish after major revisions noted.
>
>Comments:
>1. The authors need to reference recent work by Adame on constrained polymer effects.
>2. The authors also need to look at work on ion-dipole interactions with clay by Goss etal.
>3. The x-ray diffraction patterns have been misinterpreted both systems are intercalated.
>4. The TEM pictures also show an intercalated system not exfoliated.
>5. The intercalate in the above the isoelectric point are interacting through ion-dipole bonding and below via electrostatic.
>
>Additional Questions:
>Please rate the overall importance of this manuscript to the field of biomacromolecules (10 ¨C High Importance/ 1 ¨C Low Importance): 5
>
>Please rate the element of novelty in the research reported (10 - High Novelty / 1 - Low Novelty): 5
>
>Please rate the interest to scientists working in the field of biomacromolecules (10 - High Interest / 1 - Low Interest): 6
>
>Please rate the focus of the manuscript on the interface of polymer science and the biological sciences (10 - High Focus / 1 - Low Focus): 6
>
>Are the conclusions adequately supported by the data presented?: No
>
>Are any compounds reported adequately characterized?: No

Reviewer: 2
>
>Recommendation: Publish after minor revisions noted.
>
>Comments:
>This is a carefully written paper on a topic of interest to the readers of Biomacromolecules and is suitable for publication with only minor changes.
>
>-The intensity in the cross polarization spectrum is not always quantitative.  The authors should justify their use of this approach.
>-MMT is paramagnetic.  How does this affect the results?  Could this affect the quantitative relationship in signal intensity for those signals nearest the clay?
>-Silk is renown for its mechanical properties.  The authors may wish to comment on the possibility of using the clay-silk interactions to prepare films or fibers for mechanical testing.  This is probably not possible with the lyophilized material as prepared here.
>
>
>Additional Questions:
>Please rate the overall importance of this manuscript to the field of biomacromolecules (10 ¨C High Importance/ 1 ¨C Low Importance): 8
>
>Please rate the element of novelty in the research reported (10 - High Novelty / 1 - Low Novelty): 9
>
>Please rate the interest to scientists working in the field of biomacromolecules (10 - High Interest / 1 - Low Interest): 9
>
>Please rate the focus of the manuscript on the interface of polymer science and the biological sciences (10 - High Focus / 1 - Low Focus): 8
>
>Are the conclusions adequately supported by the data presented?: Yes
>
>Are any compounds reported adequately characterized?: Yes
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