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ͶµÄÉúÎï´ó·Ö×Ó£¬Éó¸åÒâ¼ûÈçÏ£¬´ó¼Ò¾õµÃ½ÓÊܵĿÉÄÜÐÔ´óô£¿ Reviewer(s)' Comments to Author: >Reviewer: 1 > >Recommendation: Publish after major revisions noted. > >Comments: >1. The authors need to reference recent work by Adame on constrained polymer effects. >2. The authors also need to look at work on ion-dipole interactions with clay by Goss etal. >3. The x-ray diffraction patterns have been misinterpreted both systems are intercalated. >4. The TEM pictures also show an intercalated system not exfoliated. >5. The intercalate in the above the isoelectric point are interacting through ion-dipole bonding and below via electrostatic. > >Additional Questions: >Please rate the overall importance of this manuscript to the field of biomacromolecules (10 ¨C High Importance/ 1 ¨C Low Importance): 5 > >Please rate the element of novelty in the research reported (10 - High Novelty / 1 - Low Novelty): 5 > >Please rate the interest to scientists working in the field of biomacromolecules (10 - High Interest / 1 - Low Interest): 6 > >Please rate the focus of the manuscript on the interface of polymer science and the biological sciences (10 - High Focus / 1 - Low Focus): 6 > >Are the conclusions adequately supported by the data presented?: No > >Are any compounds reported adequately characterized?: No Reviewer: 2 > >Recommendation: Publish after minor revisions noted. > >Comments: >This is a carefully written paper on a topic of interest to the readers of Biomacromolecules and is suitable for publication with only minor changes. > >-The intensity in the cross polarization spectrum is not always quantitative. The authors should justify their use of this approach. >-MMT is paramagnetic. How does this affect the results? Could this affect the quantitative relationship in signal intensity for those signals nearest the clay? >-Silk is renown for its mechanical properties. The authors may wish to comment on the possibility of using the clay-silk interactions to prepare films or fibers for mechanical testing. This is probably not possible with the lyophilized material as prepared here. > > >Additional Questions: >Please rate the overall importance of this manuscript to the field of biomacromolecules (10 ¨C High Importance/ 1 ¨C Low Importance): 8 > >Please rate the element of novelty in the research reported (10 - High Novelty / 1 - Low Novelty): 9 > >Please rate the interest to scientists working in the field of biomacromolecules (10 - High Interest / 1 - Low Interest): 9 > >Please rate the focus of the manuscript on the interface of polymer science and the biological sciences (10 - High Focus / 1 - Low Focus): 8 > >Are the conclusions adequately supported by the data presented?: Yes > >Are any compounds reported adequately characterized?: Yes |
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