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ͨ¹ýµ÷½Ú»ùÖÊ×é·Ö±ÈÀý£¬Ñо¿ÁËSrAl2xO3x+1:Eu2+,Dy3+£¨x=1~2£©Ó«¹â·Û¾§Ìå½á¹¹£¬·¢¹âÐÔÖʼ°³¤Óà»ÔÌØÐÔ¡£Ñ¡È¡ÏõËáïȺÍÏõËáÂÁ×÷Ϊ»ùÖÊÔ­²ÄÁÏ£¬ÅðËá°±ºÍ·ú»¯ÂÁ×÷ΪÖúÈܼÁ£¬²ÉÓÃÑôÀë×Ó²ÝËáÑι²³Áµí¡¢Êª·¨»ìºÏ¼°·Ö²½ºÏ³ÉµÈ·½·¨£¬ÖƱ¸ÁËÁÁ¶È¸ß¡¢Óà»Ô³¤¼°Á¼ºÃÁ£¾¶·Ö²¼µÄϵÁг¤Óà»Ô·¢¹â²ÄÁÏ¡£»ùÓÚ¶ÔÑùÆ·XÉäÏßÑÜÉäͼÆ×£¬¼¤·¢¡¢·¢Éä¹âÆ×ºÍÓà»ÔË¥¼õÇúÏß²âÁ¿¼°·ÖÎö£¬·¢ÏÖSrAl2xO3x+1: Eu2+,Dy3+¾ßÓÐÁ¼ºÃµÄ½á¾§×´Ì¬£»ËæxÔö¼Ó£¬·¢Éä¹âÆ×·åÖµ´Ó520nmÀ¶ÒÆÖÁ470nm£»Ë¥¼õµ½¿É±æÈÏ·¢¹âÇ¿¶È0.32mcd/m2Óà»Ôʱ¼ä¿ÉÏàÓ¦µØ´Ó30hÑÓ³¤µ½60hÒÔÉÏ¡£±íÏÖ²»Í¬Óà»ÔÌØÐÔµÄÖ÷ÒªÔ­ÒòÊÇEu2+ÔÚ»ùÖÊÖоßÓв»Í¬Å¨¶È¡¢²»Í¬Ë¥¼õËٶȵÄÀ¶¡¢ÂÌÁ½ÖÖ·¢¹âÖÐÐÄÔì³ÉµÄ£¬ÆäÖÐÀ¶·¢¹âÖÐÐÄÊÙÃüÃ÷ÏÔ¸ßÓÚÂÌ·¢¹âÖÐÐÄ¡£

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By adjusting the proportion of host composition, the crystal structure, luminescent properties and long afterglow characteristics of phosphor SrAl2xO3x+1: Eu2+, Dy3+(x=1~2) are studied. Selecting strontium nitrate and aluminum nitrate as raw materials of host, ammonium borate and aluminum fluoride as fluxes, and using cationic oxalic acid co-precipitation, wet mixing, stepwise synthesis etc., a series of long-afterglow phosphors with high-brightness, long duration time and good particle-size distribution are prepared. Based the analyses on X-ray diffraction pattern, excitation and emission spectra, and afterglow decay curve of the sample, it is found that SrAl2xO3x+1: Eu2+, Dy3+ has a good crystal structure; the emission peak show blueshift from 520nm to 470nm as x increase; The afterglow time for attenuation to recognizable luminous intensity (0.32mcd/m2) can be extended from 30h to above 60h. The main reason of different afterglow is that there are two Eu2+ luminous centers (blue and green-emitting) with different concentration and different fluorescence-decay time in the host. The fluorescence lifetime of blue-emitting center is apparently higher than that of the green-emitting one.
8Â¥2009-08-24 18:00:32
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168yjh(½ð±Ò+5,VIP+0):лл²ÎÓë 8-24 17:55
By adjusting the matrix component proportion£¬research the phosphor crystal structure of SrAl2xO3x+1:Eu2+,Dy3+£¨x=1~2£©, luminance and persistence characteristic.Select strontium nitrate and aluminium nitrate as stroma materials, use AmmoniumBorate and aluminium fluoride as latent solvent, synthesis series of long-lasting phosphor by the stepwise synthesis and  co-precipitates of oxalates ,wet-mixing. the long-lasting phosphor in the paper having the qualities of High brightness,long afterglow, Good particle size distribution.
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3Â¥2009-08-23 13:15:42
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The Xs and emission spectrum results showed that SrAl2xO3x+1: Eu2+,Dy3+ have good crystallizationcan , with the x increasing he excited from 520nm to 470nm.
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