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Considering the strong ¦Ð-conjugated effect of the rigid coplanar Py 2 TTz ligand and d 10 electron configuration of central metal ions, compounds 1 and 2 are likely to exhibit good fluorescent properties. Thus, the fluorescent properties of free ligand and compounds 1 and 2 were investigated. As shown in Figure S7, the free ligand Py 2 TTz exhibits two emission peaks at 440 nm and 451 nm upon excitation at 413 nm in the solid state, which can be assigned to ¦Ð*-¦Ð transition. 68-69 Upon excitation at 414 nm for compound 1 and 417 nm for compound 2, the emission peaks of compounds 1 and 2 in powder samples appear at 453 nm and 518 nm, respectively. Compared with the free ligand Py 2 TTz, the emission peak of compound 1 is slightly red shifted, which can be attributed to metal perturbed emission of ligand. However, compound 2 displays a large red shift of 67 nm, which may be assigned to the ligand- to-metal charge transfer (LMCT). 70-71 |
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2Â¥2018-10-22 20:43:09
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3Â¥2018-10-22 21:20:55
frankwang123
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6Â¥2018-10-22 22:13:01
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TT123456
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