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郑铭

金虫 (正式写手)

[交流] 求助文献一篇(有效期至2009.03.25)

求助文献一篇
Cho,C.S.; Itotani, K.; Uemura, S. J. Organomet. Chem. 1993,443,253

邮箱:zheng334708@yahoo.com.cn

[ Last edited by 郑铭 on 2009-3-21 at 19:45 ]
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baidsh

木虫 (小有名气)

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郑铭(金币+4,VIP+0):谢谢. 3-22 17:22
此杂志似乎从1995年开办的吧?Journal of Organometallic Chemistry 1995-  (Elsevier)
3楼2009-03-22 01:13:54
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ryhq


郑铭(金币+1,VIP+0):谢谢! 3-22 17:22
好想帮你,可是不知道啊
友情顶贴,希望你早日找到答案@@@@
2楼2009-03-21 22:03:52
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hsf81105

金虫 (正式写手)

4楼2009-03-22 07:14:33
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huangdiank

金虫 (正式写手)


郑铭(金币+1,VIP+0):谢谢! 3-22 17:20
Sodium tetraphenylborate as a phenylating reagent in the palladium-catalyzed phenylation of alkenes and acid chlorides

chan Sik Cho, Koichi Itotani and Sakae Uemura

Abstract
Sodium tetraphenylborate (NaBPh4) reacts with terminal alkenes in acetic acid at 25°C in the presence of a catalytic amount of palladium(II) acetate together with silver acetate as a re-oxidant to give the corresponding phenylated alkenes in 22–87% yield. It also reacts with acid chlorides in tetrahydrofuran (THF) at 25°C in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) to give the corresponding phenyl ketones in 51–100% yield. Carbonylation of the borate with 1–30 atm carbon monoxide (CO) in methanol at 25°C in the presence of palladium(II) acetate or sodium chloropalladate (Na2PdCl4) affords a low yield (9–30%) of benzophenone and methyl benzoate, a higher pressure favoring the formation of the latter.

Journal of Organometallic Chemistry
Volume 443, Issue 2, 26 January 1993, Pages 253-259
搞不定呀,很想帮你的
6楼2009-03-22 10:47:28
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