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我的问题自己在这篇文献找到答案了,分享出来希望能帮助和我一样对MOF中拓扑结构困惑的人
Metal–organic framework structures – how closely are they related to classical inorganic structures?
DOI: 10.1039/B815106G (Tutorial Review) Chem. Soc. Rev., 2009, 38, 2304-2318
http://pubs.rsc.org.libsw.nuk.ed ... ml/2009/cs/b815106g
这里是文献的abstract
Metal–organic frameworks (MOFs) have emerged as an important family of compounds for which new properties are increasingly being found. The potential for such compounds appears to be immense, especially in catalysis, sorption and separation processes. In order to appreciate the properties and to design newer frameworks it is necessary to understand the structures from a fundamental perspective. The use of node, net and vertex symbols has helped in simplifying some of the complex MOF structures. Many MOF structures are beginning to be described as derived from inorganic structures. In this tutorial review, we have provided the basics of the node, the net and the vertex symbols and have explained some of the MOF structures. In addition, we have also attempted to provide some leads towards designing newer structures/topologies.
金属有机骨架(MOFs)已经成为一个重要的化合物家族,新的特性越来越多地被发现。这种化合物的潜力似乎是巨大的,特别是在催化,吸附和分离过程中。为了理解这些属性并设计更新的框架,有必要从基本角度理解结构。节点,网络和顶点符号的使用有助于简化一些复杂的MOF结构。许多MOF结构开始被描述为源自无机结构。在本教程中,我们提供了节点的基础知识,网络和顶点符号,并解释了一些MOF结构。另外,我们还试图为设计更新的结构/拓扑提供一些线索。 @我想更懂你29 |
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