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hslining

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[资源] 【材料版系列跨年活动】分享08年行业内的牛文献,3-5金币奖励


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[ Last edited by hslining on 2009-1-3 at 10:16 ]
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nihaoczh

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★ ★ ★
hslining(金币+3):过年好! 2-2 10:47
固态能源
【题目】High Energy Density All-Solid-State Batteries: A Challenging
Concept Towards 3D Integration                          
【作者】Loıc Baggetto, Rogier A. H. Niessen, Fred Roozeboom, and Peter H. L. Notten
【摘要】Rechargeable all-solid-state batteries will play a key role in many autonomous devices. Planar solid-state thin film batteries are rapidly emerging but reveal several drawbacks, such as a relatively low energy density and the use of highly reactive metallic lithium. In order to overcome these limitations a new 3D-integrated all-solid-state battery concept with significantly increased surface area is presented. By depositing the active battery materials into high-aspect ratio structures etched in, for example silicon, 3D-integrated all-solid-state batteries are calculated to reach a much higher energy density. Additionally, by adopting novel high-energy dense Li-intercalation materials the use of metallic Lithium can be avoided. Sputtered Ta, TaN and TiN films have been investigated as potential Li-diffusion barrier materials. TiN combines a very low response towards ionic Lithium and a high
electronic conductivity. Additionally, thin film poly-Si anodes have been electrochemically characterized with respect to their thermodynamic and kinetic Li-intercalation properties and cycle life. The Butler-Vollmer relationship was successfully applied, indicating favorable electrochemical charge transfer kinetics and solid-state diffusion. Advantageously, these new Li-intercalation anode materials were found to combine an extremely high energy density with fast rate capability, enabling future 3D-integrated
all-solid-state batteries.
【刊名及期卷】Adv. Funct. Mater. 2008, 18, 1057–1066
【下载链接】High Energy Density All-Solid-State Batteries A Challenging Concept Towards 3D Integration Adv. Funct. Mater. 2008_ 18_ 1057–1066.pdf

[ Last edited by nihaoczh on 2009-1-14 at 20:27 ]
11楼2009-01-14 20:21:39
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monicajing

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纳米镍粉(金币+3,VIP+0):有下载的链接吗?先谢谢了
【题目】Matching Glass-Forming Ability with the Density of the Amorphous Phase
【作者】Y. Li,1,2* Q. Guo,1,2 J. A. Kalb,1,3 C. V. Thompson1,3*
【刊名及期卷】Science 19 December 2008: Vol. 322. no. 5909, pp. 1816 - 1819
【摘要】
The density of the amorphous phase of metals is generally thought to be related to glass formation, but this correlation has not been demonstrated experimentally to date. In this work, systematic deflection measurements using microcantilevers and a combinatorial deposition method show a correlation between glass-forming ability and the density change upon crystallization over a broad compositional range in the copper-zirconium binary system. Distinct peaks in the density of the amorphous phase were found to correlate with specific maxima in the critical thickness for glass formation. Our findings provide quantitative data for the development of structural models of liquids that are readily quenched to the amorphous state. The experimental method developed in this work can facilitate the search for new glass-forming alloys.
2楼2009-01-02 20:37:20
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hslining

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http://www.sciencemag.org/cgi/reprint/322/5909/1816.pdf
引用回帖:
Originally posted by monicajing at 1/2/09 20:37:
【题目】Matching Glass-Forming Ability with the Density of the Amorphous Phase
【作者】Y. Li,1,2* Q. Guo,1,2 J. A. Kalb,1,3 C. V. Thompson1,3*
【刊名及期卷】Science 19 December 2008: Vol. 322. n ...

3楼2009-01-03 10:04:33
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seek269

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hslining(金币+3,VIP+0):原创,鼓励!
【题目】Crystal chemistry and Calphad modeling of the r phase
【作者】J.-M. Joubert
【摘要】A systematic review of the crystal chemical properties of the r phase is presented, with special
emphasis on the atomic order, i.e. the distribution of the atoms on the different sites of the crystal
structure. The data available in the literature have been systematically assessed, and are complemented
by an experimental investigation in the following systems: Al–Nb, Al–Ta, Cr–Mn, Cr–Os,
Cr–Re, Cr–Ru, Co–Mo, Fe–Mo, Fe–Re, Mn–Mo, Mn–Re, Mn–V, Mo–Re, Nb–Pt, Nb–Re, Ni–
V, Pd–Ta, Re–V, Rh–Ta and Ru–W. The properties are analyzed as a function of composition
and the nature and atomic size of the elements involved. The possibility of an order–disorder transition
has also been reviewed and completed by diffraction experiments in two systems (Cr–Mn and
Ni–V). First-principles calculations on the r phase are reviewed in line with the Calphad approach.
An analysis of the literature data concerning the Calphad modeling of systems involving the r phase
has been made. The different models used are presented and discussed. The conclusions of crystal
structure data analysis are used to make some recommendations about the choice of a model in
the frame of a Calphad assessment.
【刊名及期卷】Progress in Materials Science 53 (2008) 528–583
【下载链接】http://www.namipan.com/d/Hartsch ... 8500605f3a5e1716a00
4楼2009-01-04 11:03:12
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