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作者: Qing MA, Ping-sheng WANG, Guan LUO, Mao-ping WEN, Da-yuan GAO, Bao-hui ZHENG, Yuan-jie SHU 文题: Microstructure, Mechanical and Detonation Properties of Elastomeric Micro/Ultrafine-rubber Modified TNT-based Molten Energetic Composites 期刊名: Central European Journal of Energetic Materials 期刊年份: 2015 卷(期),起止页码: Volume 12, Number 4,723-743 |
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https://apps.webofknowledge.com/ ... age=1&doc=1 Microstructure, Mechanical and Detonation Properties of Elastomeric Micro/Ultrafine-rubber Modified TNT-based Molten Energetic Composites 作者:Ma, Q (Ma, Qing)[ 1,2 ] ; Wang, PS (Wang, Ping-sheng)[ 2 ] ; Luo, G (Luo, Guan)[ 2 ] ; Wen, MP (Wen, Mao-ping)[ 2 ] ; Gao, DY (Gao, Da-yuan)[ 2 ] ; Zheng, BH (Zheng, Bao-hui)[ 2 ] ; Shu, YJ (Shu, Yuan-jie)[ 3 ] CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS 卷: 12 期: 4 页: 723-743 出版年: 2015 查看期刊信息 CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS 出版商 INST INDUSTRIAL ORGANIC CHEMISTRY, 6 ANNOPOL ST, WARSAW, 03-236, POLAND ISSN: 1733-7178 研究领域 Chemistry Engineering 摘要 Elastomeric micro-and ultrafine-rubber are first considered as binders in melt-cast explosives for improving the mechanical properties. Acrylonitrile-butadiene rubber (NBR), in ultrafine fully vulcanized form (UF-NBR), carboxylated acrylonitrile-butadiene rubber (CNBR), in ultrafine fully vulcanized form (UF-CNBR), styrene-butadiene rubber (SBR), in ultrafine fully vulcanized form (UF-SBR), carboxylated styrene-butadiene rubber (CSBR), in ultrafine fully vulcanized form (UF-CSBR), acrylic rubber (ACM), in ultrafine fully vulcanized form (UF-ACM), room temperature vulcanized silicone rubber (RTV), in ultrafine fully vulcanized form (UF-RTV) and polytetrafluoroethene (PTFE) in micro-rubber form (PTFE-M) were utilized for modifying 2,4,6-trinitrotoluene (TNT) based melt-cast explosives. Based on their dispersity in TNT and RDX slurry, only UF-NBR, UF-CNBR and PTFE-M can be used. In the modification experiment, their influence on the mechanical and detonation performance of the matrixes were studied, as well as the impact sensitivity. Compared with PTFE-M and UF-CNBR, UF-NBR improved the tensile and compressive strength of the original formulation CYCLOTOL-65/35. The toughening mechanism was also explained through interfacial interactions and fracture energy analysis. The predicted detonation properties of the modified formulations (detonation pressure variations from 26 to 28 GPa, detonation velocity variations from 7900 to 8100 m/s) are at the same energy level as CYCLOTOL-65/35. In addition, the drop hammer impact testing results confirm that the formulation containing UF-NBR is more sensitive than the one with UF-CNBR, with the same amount of additive. 关键词 作者关键词:micro and ultrafine rubber; 2,4,6-trinitrotoluene; molten energetic composites; mechanical property; detonation performance KeyWords Plus:EXPLOSIVES; SENSITIVITY; PERFORMANCE; TOUGHNESS; POWDER 作者信息 通讯作者地址: Ma, Q (通讯作者) Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China. 增强组织信息的名称 Nanjing University of Science & Technology 地址: [ 1 ] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China 增强组织信息的名称 Nanjing University of Science & Technology [ 2 ] China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China 增强组织信息的名称 Chinese Academy of Engineering Physics [ 3 ] Xian Modern Chem Res Inst, Xian 710065, Peoples R China 增强组织信息的名称 Xi'an Modern Chemistry Research Institute 电子邮件地址:zhengbaohui305@163.com; syjfree@sohu.com 基金资助致谢 基金资助机构 授权号 Foundation of National Natural Science Foundation of China China Academy of Engineering Physics (NSAF) 11076002 National Natural Science Foundation of China (NSFC) 51373159 11402237 查看基金资助信息关闭基金资助信息 This investigation received financial assistance from the Foundation of National Natural Science Foundation of China and China Academy of Engineering Physics (NSAF, Grant No. 11076002), and the National Natural Science Foundation of China (NSFC, Grant Nos. 51373159 and 11402237). All of the authors wish to repeat their thanks to Chuanlan He for the mechanical testing and Wen Wen for the drop hammer impact testing. 出版商 INST INDUSTRIAL ORGANIC CHEMISTRY, 6 ANNOPOL ST, WARSAW, 03-236, POLAND 类别 / 分类 研究方向:Chemistry; Engineering Web of Science 类别:Chemistry, Applied; Engineering, Chemical 文献信息 文献类型:Article 语种:English 入藏号: WOS:000369524900007 ISSN: 1733-7178 其他信息 IDS 号: DC9EW Web of Science 核心合集中的 "引用的参考文献": 37 Web of Science 核心合集中的 "被引频次": 0 JCR® 类别 JCR 分区 CHEMISTRY, APPLIED Q3 ENGINEERING, CHEMICAL Q3 数据来自第 2015 版 Journal Citation Reports® |
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