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作者:
Qing MA, Ping-sheng WANG, Guan LUO, Mao-ping WEN, Da-yuan GAO, Bao-hui ZHENG, Yuan-jie SHU
文题:
Microstructure, Mechanical and Detonation Properties of Elastomeric Micro/Ultrafine-rubber Modified TNT-based Molten Energetic Composites
期刊名:
Central European Journal of Energetic Materials
期刊年份:
2015
卷(期),起止页码:
Volume 12, Number 4,723-743

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king985: 金币+5, ★★★★★最佳答案 2016-09-21 22:29:21
lazy锦溪: LS-EPI+1 2016-09-22 12:42:07
https://apps.webofknowledge.com/ ... age=1&doc=1
Microstructure, Mechanical and Detonation Properties of Elastomeric Micro/Ultrafine-rubber Modified TNT-based Molten Energetic Composites
作者:Ma, Q (Ma, Qing)[ 1,2 ] ; Wang, PS (Wang, Ping-sheng)[ 2 ] ; Luo, G (Luo, Guan)[ 2 ] ; Wen, MP (Wen, Mao-ping)[ 2 ] ; Gao, DY (Gao, Da-yuan)[ 2 ] ; Zheng, BH (Zheng, Bao-hui)[ 2 ] ; Shu, YJ (Shu, Yuan-jie)[ 3 ]


CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS


卷: 12
期: 4
页: 723-743
出版年: 2015

查看期刊信息

CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS  

出版商 INST INDUSTRIAL ORGANIC CHEMISTRY, 6 ANNOPOL ST, WARSAW, 03-236, POLAND

ISSN: 1733-7178

研究领域 Chemistry
Engineering



摘要
Elastomeric micro-and ultrafine-rubber are first considered as binders in melt-cast explosives for improving the mechanical properties. Acrylonitrile-butadiene rubber (NBR), in ultrafine fully vulcanized form (UF-NBR), carboxylated acrylonitrile-butadiene rubber (CNBR), in ultrafine fully vulcanized form (UF-CNBR), styrene-butadiene rubber (SBR), in ultrafine fully vulcanized form (UF-SBR), carboxylated styrene-butadiene rubber (CSBR), in ultrafine fully vulcanized form (UF-CSBR), acrylic rubber (ACM), in ultrafine fully vulcanized form (UF-ACM), room temperature vulcanized silicone rubber (RTV), in ultrafine fully vulcanized form (UF-RTV) and polytetrafluoroethene (PTFE) in micro-rubber form (PTFE-M) were utilized for modifying 2,4,6-trinitrotoluene (TNT) based melt-cast explosives. Based on their dispersity in TNT and RDX slurry, only UF-NBR, UF-CNBR and PTFE-M can be used. In the modification experiment, their influence on the mechanical and detonation performance of the matrixes were studied, as well as the impact sensitivity. Compared with PTFE-M and UF-CNBR, UF-NBR improved the tensile and compressive strength of the original formulation CYCLOTOL-65/35. The toughening mechanism was also explained through interfacial interactions and fracture energy analysis. The predicted detonation properties of the modified formulations (detonation pressure variations from 26 to 28 GPa, detonation velocity variations from 7900 to 8100 m/s) are at the same energy level as CYCLOTOL-65/35. In addition, the drop hammer impact testing results confirm that the formulation containing UF-NBR is more sensitive than the one with UF-CNBR, with the same amount of additive.

关键词
作者关键词:micro and ultrafine rubber; 2,4,6-trinitrotoluene; molten energetic composites; mechanical property; detonation performance

KeyWords Plus:EXPLOSIVES; SENSITIVITY; PERFORMANCE; TOUGHNESS; POWDER

作者信息
通讯作者地址: Ma, Q (通讯作者) Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China.
  增强组织信息的名称
    Nanjing University of Science & Technology  


地址:  [ 1 ] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
  增强组织信息的名称
    Nanjing University of Science & Technology  
[ 2 ] China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China
  增强组织信息的名称
    Chinese Academy of Engineering Physics  
[ 3 ] Xian Modern Chem Res Inst, Xian 710065, Peoples R China
  增强组织信息的名称
    Xi'an Modern Chemistry Research Institute  


电子邮件地址:zhengbaohui305@163.com; syjfree@sohu.com

基金资助致谢
基金资助机构 授权号
Foundation of National Natural Science Foundation of China   
China Academy of Engineering Physics (NSAF)  11076002  
National Natural Science Foundation of China (NSFC)  51373159
11402237  
查看基金资助信息关闭基金资助信息   

This investigation received financial assistance from the Foundation of National Natural Science Foundation of China and China Academy of Engineering Physics (NSAF, Grant No. 11076002), and the National Natural Science Foundation of China (NSFC, Grant Nos. 51373159 and 11402237). All of the authors wish to repeat their thanks to Chuanlan He for the mechanical testing and Wen Wen for the drop hammer impact testing.

出版商
INST INDUSTRIAL ORGANIC CHEMISTRY, 6 ANNOPOL ST, WARSAW, 03-236, POLAND

类别 / 分类
研究方向:Chemistry; Engineering

Web of Science 类别:Chemistry, Applied; Engineering, Chemical

文献信息
文献类型:Article

语种:English

入藏号: WOS:000369524900007

ISSN: 1733-7178

其他信息
IDS 号: DC9EW

Web of Science 核心合集中的 "引用的参考文献": 37

Web of Science 核心合集中的 "被引频次": 0

JCR® 类别 JCR 分区
CHEMISTRY, APPLIED  Q3
ENGINEERING, CHEMICAL  Q3


数据来自第 2015 版 Journal Citation Reports®
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