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genhunter

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2楼: Originally posted by genhunter at 2016-09-09 10:52:56
We found that when the Al content in the glass was 1 mol%, the specimens only emitted light at wavelength of 590 and 610nm, characteristic of  a 5D0→7FJ(J=1,2) energy jump of electrons in Eu3+. Furt ...

We found that when the Al content in the glass was 1 mol%, the specimens only emitted light at wavelengths of 590 and 610 nm, characteristic of  a 5D0→7FJ(J=1,2) energy jump of electrons in Eu3+. Further increase the Al content in glass matrix led to a new broad blue-green light emission around  400-550 nm, which can be assigned to 5d-4f energy jump of electrons in Eu2+. Furthermore, the Eu2+-specific broad band emission maximized at 10%Al content, while at the same time, the emission from Eu3+ decreased steadily as the Al content increased.  We therefore believe that the presence of Al in aluminosilicate glass triggered an Eu3+→Eu2+ reduction reaction.
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3楼2016-09-09 10:55:41
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