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Iron makes up about 6.3% of the Earth's crust; however it is never found in pure form, but instead, combined with other elements, especially oxygen, yielding iron oxides. These iron compounds possess distinct properties such as coloration, resulting from electron transitions between the d (t2gand eg) orbitals. These colors include yellows and reds, which are responsible for soil colors [1,2].
In living organisms, iron oxides are responsible for the activities of many enzymes, and in this way, they can be applied in biomedicine. Synthetic iron oxides are of great importance in many elds. Some oxides are used as catalysts, in redox processes and as pigments [3e8]. They are used to dye paper, rubber, plastics and cement, paint components, varnishes and enamels, because of the range of colors (yellow, brown, red, etc.) that can be obtained [9].
The colors of synthetic iron oxides differ depending on the method and conditions employed [8e16], as for each oxide or oxide hydroxide phase a speci c method is necessary. No reporting was found in the literature regarding the synthesis of different types of iron oxides employing different forced hydrolysis temperatures in order to obtain pigments with different colors.
This article presents the identi cation of iron oxide hydroxides synthesized at different temperatures of forced hydrolysis (thermohydrolysis), beginning with inorganic precursors iron (III) chloride hexahydrate (FeCl3•6H2O) and iron (III) nitrate nonahydrate(Fe(NO3)3•9H2O). These syntheses yielded nanoparticles with a slight change in the composition that is responsible for the colors in these oxide hydroxides. The principal properties studied were thermal behavior, size distribution, morphology and chemical composition. The instrumental techniques used for characterization were thermogravimetric analysis, energy dispersive spectroscopy, Raman spectroscopy and X-ray diffractometry. Particle size was determined through dynamic light scattering and X-ray diffractometry. Colors were attributed through electronic spectroscopy.
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