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[资源] ★★★★2015超级贴二〇五四《Active Plasmonic Nanomaterials》

书名Active
Plasmonic
Nanomaterials
作者Luciano De Sio
页数407
出版社CRC Press
International Standard Book Number-13: 978-981-4613-01-9 (eBook - PDF)Preface xv
1 Plasmonics: A Theoretical Background 1
Luigia Pezzi, Giovanna Palermo, and Cesare Umeton
1.1 Introduction 1
1.2 Electromagnetism of Metals 7
1.3 Surface Plasmon Polariton 15
1.4 Localized Surface Plasmon 22
2 Synthesis and Surface Engineering of Plasmonic
Nanoparticles 33
Roberto Comparelli, Tiziana Placido, Nicoletta Depalo,
Elisabetta Fanizza, Marinella Striccoli,
and M. Lucia Curri
2.1 Introduction 34
2.2 Experimental Parameter Affecting Plasmon
Absorption 36
2.2.1 Size Dependence of Plasmon Absorption:
Mie’s Theory 37
2.2.2 Shape-Dependence of Plasmon Absorption:
Gans Theory and Discrete Dipole
Approximation 38
2.2.3 Other Parameters Affecting Plasmon
Absorption 40
2.2.3.1 Effect of surrounding medium: the
Drude model 40
2.2.3.2 Effect of interparticle coupling 41
2.2.3.3 Effect of temperature 41
2.3 Nanoparticle Characterization 42
© 2016 by Taylor & Francis Group, LLC
viii Contents
2.4 Synthesis of Hydrophilic Plasmonic Nanoparticles 44
2.4.1 Synthesis of Spherical Nanoparticles 44
2.4.1.1 Turkevich method and its
modifications 45
2.4.1.2 Seed-mediated method 46
2.4.1.3 Photochemical synthesis of spherical
metal nanoparticles 47
2.4.2 Shape Control of Metal Nanoparticles 49
2.4.2.1 Gold nanorods 49
2.4.2.2 Silver nanorods/wires 58
2.4.3 Other Shapes 59
2.5 Synthesis of Hydrophobic Plasmonic Nanoparticles 60
2.5.1 Hydrophobic Spherical Metal Nanoparticles 61
2.5.2 Shape Control in Organic Media 62
2.6 Nanoseparation and Purification Techniques: Size
and/or Shape Sorting of Plasmonic Nanoparticles 63
2.6.1 Gel Electrophoresis 63
2.6.2 Centrifugation 64
2.6.3 Size-Selective Precipitation 65
2.6.4 Chromatographic Separations 67
2.6.5 Filtration 67
2.7 Surface Modification of Plasmonic Nanoparticles 68
2.7.1 Post-Synthesis Functionalization 68
2.7.2 Post-Synthesis Functionalization for Phase
Transfer 70
2.7.3 Growth of a Silica Shell 73
2.7.3.1 Growth of silica shell onto hydrophilic
nanoparticles 75
2.7.3.2 Growth of silica shell onto
hydrophobic nanoparticles 80
2.8 Conclusion 82
3 Amorphous Nanoparticle Assemblies by Bottom-Up
Principles 101
Alastair Cunningham, Mahshid Chekini, and Thomas B¨urgi
3.1 Introduction 101
3.2 Electrostatic Forces 104
3.3 Assembly of Nanoparticles on Flat Surfaces 105
© 2016 by Taylor & Francis Group, LLC
Contents ix
3.4 Building Up the Third Dimension 109
3.5 Core–Shell Structures 115
3.6 Conclusion 118
4 Optimizing Surfactant on Nanoparticles 123
Hari M. Atkuri, Ke Zhang, and John L. West
4.1 Introduction 123
4.2 Role of Surfactant 124
4.2.1 States of Surfactant 125
4.2.2 Surfactant IR Absorption Band 126
4.3 Experiment 128
4.4 Results and Discussion 130
4.5 Summary 140
5 A Brief Overview on Synthesis and Characterization of
Nanomaterials 143
Ariel Meneses-Franco, Eduardo Soto-Bustamante,
and Marcelo Kogan-Bocian
5.1 Introduction 144
5.2 Major Methods of Chemical Synthesis of
Nanoparticles 145
5.2.1 Precipitation 145
5.2.2 Solvothermolysis and Recrystallization 146
5.2.3 Sol-Gel Nanoparticles Synthesis 148
5.3 Biosynthetic Methods: The Use of Microorganisms
and Plants 150
5.3.1 Bacteria 151
5.3.2 Yeast and Fungus 152
5.3.3 Plants 153
5.4 Characterization of Nanomaterials 153
5.4.1 Transmission Electron Microscopy 154
5.4.2 Scanning Electron Microscopy 155
5.4.3 Scanning Probe Microscopy 157
5.4.4 X-Ray Diffraction 158
5.4.5 X-Ray Photoelectron Spectroscopy 160
5.4.6 Dynamic Light Scattering 161
5.4.7 Zeta Potential 162
© 2016 by Taylor & Francis Group, LLC
x Contents
6 Plasmon–Gain Interplay in Metastructures 171
Antonio De Luca, Melissa Infusino, Alessandro Veltri,
Kandammathe V. Sreekanth, Roberto Bartolino,
and Giuseppe Strangi
6.1 Introduction: Background and Significance 171
6.2 Plasmon–Gain Interplay: Theory and Modeling 174
6.2.1 Single Spherical Nanoparticle 175
6.2.2 Core–Shell Spherical Nanoparticles 179
6.2.3 Plasmonic Mesocapsules 181
6.2.4 Effective Medium Theory 184
6.3 Systems and Approaches Across Scales 186
6.3.1 Nanoscale Approach 187
6.3.2 Mesoscale Approach 197
6.3.3 Macroscale Approach 201
6.4 Summary 207
7 Localized Surface Plasmons: A Powerful Tool for Sensing 215
Francesco Todescato
7.1 What Are Plasmons? 215
7.1.1 Dielectric Functions of Metals: The Drude
Model 217
QQ截图20150803230723.jpg
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