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sunshan4379
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Accession number: 20151200671168 Title: Synthesis of functionalized ¦Ã-lactones via a three-component cascade reaction catalyzed by consecutive N-heterocyclic carbene systems Authors: Zhao, Qian1 ; Han, Bo2 ; Wang, Biao1 ; Leng, Hai-Jun2 ; Peng, Cheng1, 2 ; Huang, Wei1 Author affiliation: 1 Ministry of Education Key Laboratory of Standardization of Chinese Medicine, School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu, China 2 State Key Laboratory Breeding Base of Systematic Research, Development and Utilization of Chinese Medicine Resources, Chengdu University of Traditional Chinese Medicine, Chengdu, China Corresponding author: Peng, Cheng Source title: RSC Advances Abbreviated source title: RSC Adv. Volume: 5 Issue: 34 Issue date: 2015 Publication year: 2015 Pages: 26972-26976 Language: English E-ISSN: 20462069 CODEN: RSCACL Document type: Journal article (JA) Publisher: Royal Society of Chemistry Abstract: Two consecutive N-heterocyclic carbene (NHC) catalytic systems were combined in a one-pot cascade reaction for the assembly of aromatic aldehydes and 2-haloenals into a structurally complex ¦Ã-lactone backbone. To our knowledge, this is the first report of NHC-catalyzed [3 + 2] annulation of ¦Á,¦Â-unsaturated acylazoliums with 1,2-bisnucleophiles. © The Royal Society of Chemistry 2015. Number of references: 70 Main heading: Synthesis (chemical) Controlled terms: Catalysis - Esters - Organic compounds Uncontrolled terms: Aromatic aldehyde - Cascade reactions - Catalytic system - Functionalized - N-heterocyclic carbenes - One pot - Three component Classification code: 802.2 Chemical Reactions - 804.1 Organic Compounds DOI: 10.1039/c5ra01254f Database: Compendex Compilation and indexing terms, © 2015 Elsevier Inc. |

2Â¥2015-05-21 15:20:50
sunshan4379
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3Â¥2015-05-21 15:21:02















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