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分享一本好书《Self-cleaning Materials and Surfaces-A Nanotechnology Approach》
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铛铛铛铛，好书来喽 wiely上13年书《Self-cleaning Materials and Surfaces-A Nanotechnology Approach》 内容详细，包括自清洁材料及表面的定义、应用、各种材料及其制备方法，也包括该领域的最新研究进展。 目录如下： PART I CONCEPTS OF SELF-CLEANING SURFACES 1 Superhydrophobicity and Self-Cleaning 3 Paul Roach and Neil Shirtcliffe 1.1 Superhydrophobicity 3 1.1.1 Introducing Superhydrophobicity 3 1.1.2 Contact Angles and Wetting 4 1.1.3 Contact Angle Hysteresis 4 1.1.4 The Effect of Roughness on Contact Angles 6 1.1.5 Where the Equations Come From 8 1.1.6 Which State Does a Drop Move Into? 11 1.2 Self-Cleaning on Superhydrophobic Surfaces 12 1.2.1 Mechanisms of Self-Cleaning on Superhydrophobic Surfaces 12 1.2.2 Other Factors 15 1.2.3 Nature’s Answers 17 1.2.4 Superhydrophilic Self-Cleaning Surfaces 19 1.2.5 Functional Properties of Superhydrophobic Surfaces 20 1.3 Materials and Fabrication 25 1.4 Future Perspectives 27 References 28 PART II APPLICATIONS OF SELF-CLEANING SURFACES 2 Recent Development on Self-Cleaning Cementitious Coatings 35 Daniele Enea 2.1 Introduction 35 2.2 Atmospheric Pollution: Substances and Laws 36 2.2.1 Nitrogen Oxides 36 2.2.2 Particulate Matter 37 2.2.3 Volatile Organic Compounds 37 2.3 Heterogeneous Photocatalysis 38 vi Contents 2.4 Self-Cleaning Surfaces 39 2.4.1 Mechanisms of Photo-Reduction of Air Pollutants 41 2.4.2 Some Experimental Evidences 41 2.5 Main Applications 44 2.6 Test Methods 46 2.6.1 Colour 46 2.6.2 Photocatalytic Degradation of Nitrogen Oxides 47 2.6.3 Photocatalytic Degradation of Micro-Pollutants in Air 49 2.6.4 Photocatalytic Degradation of Rhodamine B 51 2.6.5 Spectroscopic Techniques 53 2.7 Future Developments 53 References 54 3 Recent Progress on Self-Cleaning Glasses and Integration with Other Functions 57 Baoshun Liu, Qingnan Zhao and Xiujian Zhao 3.1 Introduction 57 3.2 Theoretical Fundamentals for Self-Cleaning Glasses 58 3.2.1 Wettability 58 3.2.2 Photoinduced Hydrophilicity 59 3.2.3 Heterogeneous Photocatalysis 62 3.3 Self-Cleaning Glasses Based on Photocatalysis and Photoinduced Hydrophilicity 63 3.3.1 Self-Cleaning Glasses with Pores 63 3.3.2 Doping to Realize Visible-Light-Induced Self-Cleaning Glasses 65 3.3.3 The Use of Hole Transfer to Realize Self-Cleaning 67 3.3.4 The Effect of Temperature and Atmosphere on the Photoinduced Hydrophilicity 67 3.3.5 The Effect of Soda Ions on the Properties of Self-Cleaning Glasses 69 3.3.6 The Anti-Bacterial Effect and Anti-Fogging Effect 70 3.3.7 The Composite SiO2 Films for Self-Cleaning Glasses with High Antireflection 72 3.4 Inorganic Hydrophobic Self-Cleaning Glasses 75 3.4.1 Modifying The TiO2 Film by Low-Electronegativity Elements 75 3.4.2 The Application of ZnO Material in a Superhydrophobic Material 77 3.5 Self-Cleaning Glasses Modified by Organic Molecules 79 3.6 The Functionality of Self-Cleaning Glasses 80 References 84 4 Self-Cleaning Surface of Clay Roofing Tiles 89 Jonjaua Ranogajec and Miroslava Radeka 4.1 Clay Roofing Tiles and Their Deterioration Phenomena 89 4.1.1 Raw Material Composition and Firing Process 89 Contents vii 4.1.2 Surface Characteristics of Clay Roofing Tiles 91 4.1.3 Frost, Chemical and Biocorrosion Deterioration of Clay Roofing Tiles 96 4.1.4 Simulation of Weathering of Clay Roofing Tiles in Laboratory Conditions 97 4.2 Protective and Self-Cleaning Materials for Clay Roofing Tiles 105 4.2.1 Design of Protective and Self-Cleaning Coatings 107 4.2.2 Monitoring the Characteristics of Coated Clay Roofing Tiles 113 References 123 5 Self-Cleaning Fibers and Fabrics 129 Wing Sze Tung and Walid A. Daoud 5.1 Introduction 129 5.2 Photocatalysis 130 5.2.1 Mechanisms 131 5.2.2 Titanium Dioxide Photocatalyst 132 5.3 Photocatalytic Self-Cleaning Surface Functionalization of Fibrous Materials 134 5.3.1 Self-Cleaning Cellulosic Fibers 134 5.3.2 Self-Cleaning Keratin Fibers 139 5.3.3 Self-Cleaning Synthetic Fibers 140 5.4 Application of Photocatalytic Self-Cleaning Fibers 142 5.4.1 Protective Clothing 142 5.4.2 Household Appliances and Interior Furnishing 143 5.5 Limitations 144 5.5.1 Environmental Concerns 144 5.5.2 Human Safety Concerns 144 5.5.3 Photocatalytic Efficiency and Stability 145 5.6 Future Prospects 146 5.6.1 Visible Light Activation 146 5.6.2 Remote Photocatalytic Effect 146 5.6.3 Process Modification 146 5.6.4 Empirical Measurements 147 5.7 Conclusions 147 References 147 6 Self-Cleaning Materials for Plastic and Plastic-Containing Substrates 153 Houman Yaghoubi 6.1 Introduction 153 6.2 TiO2 Thin Films on Polymers: Sol–Gel-Based Wet Coating Techniques 155 6.2.1 Wet Coating Techniques: History and Advantages 155 6.2.2 TiO2 Photocatalytic Thin Films on PC and PMMA 156 6.2.3 SiO2 Incorporation into TiO2 - SiO2 as an Interfacial Layer for TiO2 162 6.2.4 TiO2 Photocatalytic Thin Films on PET and HDPE 167 viii Contents 6.2.5 TiO2 Photocatalytic Thin Films on PS 171 6.2.6 Modified Hybrid TiO2 Sols on Plastics: ABS, Polystyrene, and PVC 172 6.2.7 TiO2 on Paints and Self-Cleaning Paints 175 6.2.8 MW Irradiation–Assisted Dip Coating for Low-Temperature TiO2 Deposition on Polymers 178 6.2.9 Nanomechanical Properties of Dipped TiO2 Granular Thin Films on Polymer Substrates 179 6.3 TiO2–Polymer Nanocomposites Review: Casting (Mixing) Techniques 181 6.3.1 Short History and Advantages 181 6.3.2 Ag/Polyethylene Glycol (PEG)–Polyurethane (PU)–TiO2 Nanocomposite Films by Solution Casting Techniques 182 6.3.3 Antimicrobial Activity of TiO2-Isotactic Polypropylene (iPP) Composites 183 6.3.4 TiO2 Immobilized Biodegradable Polymers 184 6.4 TiO2 Sputter-Coated Films on Polymer Substrates 187 6.4.1 DC Reactive Magnetron Sputtering of Photocatalytic TiO2 Films on PC 187 6.4.2 Reactive Radio-Frequency [RF] Magnetron Sputtering of Photocatalytic TiO2 Films on PET 189 6.5 TiO2 Thin Films on PET and PMMA by Nanoparticle Deposition Systems (NPDS) 190 6.6 Photo-Responsive Discharging Effect of Static Electricity on TiO2-Coated Plastic Films 192 6.7 Recent Achievements 192 6.7.1 Commercialized Products: Ube-Nitto Kasei Co. and the University of Tokyo 192 6.7.2 Patents: University of Wisconsin 193 Acknowledgements 194 References 194 PART III ADVANCES IN SELF-CLEANING SURFACES 7 Self-Cleaning Textiles Modified by TiO2 and Bactericide Textiles Modified by Ag and Cu 205 John Kiwi and Cesar Pulgarin 7.1 Introduction 205 7.2 Self-Cleaning Textiles: RF-Plasma Pretreatment to Increase the Binding of TiO2 206 7.3 Self-Cleaning Mechanism for Colorless and Colored Stains on Textiles 208 7.4 Self-Cleaning Textiles: Vacuum-UVC Pretreatment to Increase the Binding of TiO2 209 Contents ix 7.5 XPS to Follow Stain Discoloration on Cotton Modified with TiO2 and Characterization of the TiO2 Coating 212 7.6 Bactericide/Ag/Textiles Prepared by Pretreatment with Vacuum-UVC 214 7.7 DC-Magnetron Sputtering of Textiles with Ag Inactivating Airborne Bacteria 217 7.8 Inactivation of E. coli by CuO in Suspension in the Dark and Under Visible Light 218 7.9 Inactivation of E. coli by Pretreated Cotton Textiles Modified with Cu/CuO at the Solid/Air Interface 220 7.10 Direct Current Magnetron Sputtering (DC and DCP) of Nanoparticulate Continuous Cu-Coatings on Cotton Textile Inducing Bacterial Inactivation in the Dark and Under Light Irradiation 220 7.11 Future Trends 223 References 224 8 Liquid Flame Spray as a Means to Achieve Nanoscale Coatings with Easy-to-Clean Properties 229 Mikko Aromaa, Joe A. Pimenoff and Jyrki M. M¨akel¨a 8.1 Gas-Phase Synthesis of Nanoparticles 229 8.2 Aerosol Reactors 233 8.2.1 Hot Wall Reactors 233 8.2.2 Laser Reactors 234 8.2.3 Plasma Reactors 234 8.2.4 Flame Reactors 235 8.2.5 Spray Pyrolysis 236 8.3 Liquid Flame Spray 237 8.3.1 Synthesis of Nanoparticles via LFS 237 8.3.2 Multicomponent Nanoparticles 238 8.3.3 Synthesis and Deposition of Nanoparticle Coatings 240 8.4 Liquid Flame Spray in Synthesis of Easy-to-Clean Antimicrobial Coatings 243 8.4.1 Synthesis of Titanium Dioxide 243 8.4.2 Deposition of the Titania Coatings 244 8.4.3 Doping of the Coatings 246 8.4.4 Performance of the Antimicrobial Easy-to-Clean Coatings 247 8.5 Summary 249 References 249 9 Pulsed Laser Deposition of Surfaces with Tunable Wettability 253 Evie L. Papadopoulou 9.1 Introduction 253 9.2 Basic Theory of Wetting Properties of Surfaces 254 9.2.1 Planar Surfaces 254 9.2.2 Rough Surfaces 255 x Contents 9.3 Roughening a Flat Surface 256 9.3.1 PLD Technique Overview 257 9.3.2 Nanostructures Grown by PLD 257 9.4 Switchable Wettability 263 9.4.1 Photoinduced Wettability on PLD Structures 263 9.4.2 Electrowetting on PLD Structures 267 9.5 Concluding Remarks 270 References 271 10 Fabrication of Antireflective Self-Cleaning Surfaces Using Layer-by-Layer Assembly Techniques 277 Yu-Min Yang 10.1 Introduction 277 10.2 Antireflective Coatings 278 10.2.1 Interference Multiple Layers 278 10.2.2 Inhomogeneous Layer with Gradient Refractive Index 279 10.3 Solution-Based Layer-by-Layer (LbL) Assembly Techniques 280 10.3.1 Electrostatic Assembly 280 10.3.2 Langmuir–Blodgett (LB) Assembly 281 10.3.3 Self-Assembly 282 10.4 Mechanisms of Self-Cleaning 283 10.4.1 Hydrophilic Surfaces 283 10.4.2 Hydrophobic Surfaces 284 10.5 Fabrication of Antireflective Self-Cleaning Surfaces Using Electrostatic Layer-by-Layer (ELbL) Assembly of Nanoparticles 285 10.5.1 Superhydrophilic Self-Cleaning Surfaces with Antireflective Properties 285 10.5.2 Superhydrophobic Self-Cleaning Surfaces with Antireflective Properties 291 10.6 Fabrication of Superhydrophobic Self-Cleaning Surfaces Using LB Assembly of Micro-/Nanoparticles 297 10.7 Characterization of As-Fabricated Surfaces 300 10.7.1 Surface Morphology and Roughness 300 10.7.2 Thickness, Porosity, and Refractive Index 301 10.7.3 Transmittance 302 10.7.4 Photocatalytic Properties 303 10.7.5 Contact Angle and Contact Angle Hysteresis 304 10.7.6 Mechanical Stability 305 10.8 Challenges and Future Development 306 10.9 Conclusion 307 References 307 Contents xi PART IV POTENTIAL HAZARDS AND LIMITATIONS OF SELF-CLEANING SURFACES 11 The Environmental Impact of a Nanoparticle-Based Reduced Need of Cleaning Product and the Limitation Thereof 315 L. Reijnders 11.1 Introduction 315 11.1.1 Outline 315 11.1.2 Nanoparticle-Based Reduced Need of Cleaning Surfaces 316 11.2 Titania and Amorphous Silica Nanoparticles and Carbon Nanotubes Can Be Hazardous and May Pose a Risk 319 11.2.1 Molecular Mechanisms 322 11.2.2 Risk Caused by Nanoparticles 322 11.3 Environmental Impact of a Reduced Need of Cleaning Product 323 11.3.1 Direct Environmental Effects of a Nanoparticle-Based Reduced Need of Cleaning Product 324 11.3.2 Net Direct Environmental Benefits 328 11.3.3 Indirect Environmental Effects of a Nanoparticle-Based Reduced Need of Cleaning Product 329 11.4 Limiting the Direct Environmental Impact of a Nanoparticle-Based Reduced Need of Cleaning Product, Including Limitation of Risks Following from Exposure to Nanoparticles 330 11.4.1 Limiting the Direct Environmental Impact 330 11.4.2 Limitation of Risks Following from Exposure to Nanoparticles 330 11.5 Conclusion 331 References 331 Index 347  http://pan.baidu.com/s/1kTlAcMb下载地址  1119991773.jpg |
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