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1. Electrodeposition of Cu-Ga Precursor Layer from Deep Eutectic Solvent for CuGaS2 Solar Energy Thin Film
ÆÚ¿¯Ãû£ºJournal of The Electrochemical Society£¬ 2014Äê161¾í µÚ6ÆÚ¡£
2. Preparation of Cu(In,Ga)S2 Absorber Layers for Thin Film Solar Cell by Annealing of Electrodeposited Cu-Ga-S Precursor Layers
ÆÚ¿¯Ãû£º£ºJournal of The Electrochemical Society£¬ 2014Äê161¾í µÚ14ÆÚ¡£
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Electrodeposition of Cu-Ga Precursor Layer from Deep Eutectic Solvent for CuGaS2 Solar Energy Thin Film  


×÷Õß:Niu, GH (Niu, Guanghai)[ 1,2,3 ] ; Yang, S (Yang, Sui)[ 1,2,3 ] ; Li, HX (Li, Hongxing)[ 1,2,3 ] ; Yi, J (Yi, Jie)[ 4 ] ; Wang, MH (Wang, Minghao)[ 1,2,3 ] ; Lv, XX (Lv, Xinxin)[ 1,2,3 ] ; Zhong, JX (Zhong, Jianxin)[ 1,2,3 ]  




JOURNAL OF THE ELECTROCHEMICAL SOCIETY



¾í: 161

ÆÚ: 6

Ò³: D333-D338

DOI: 10.1149/2.050406jes

³ö°æÄê: 2014

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CuGaS2 solar energy thin film is fabricated with electrochemical deposition of precursor from deep eutectic solvent (DES) based on choline chloride and urea (commercially known as Reline) to eliminate the interference of hydrogen evolution reaction (HER). The process involves electrodeposition of Cu-Ga precursor on molybdenum substrate from Reline and subsequential annealing in sulfur vapor. The formation of CuGa2 alloy in precursor is observed and pure ternary chalcopyrite CuGaS2 phase in good polycrystalline structure without secondary phase is obtained after thermal treatment. The influence of applied deposition potential on the crystalline phase, morphology, compositions and carrier concentration of the films were investigated. The Cu/Ga ratio decreases with decreasing the deposition potential benefiting the formation of a pure crystallized CuGaS2 thin film. A relative positive deposition potential results in a larger crystalline size benefitting the photoelectrical conversion. Impedance spectroscopy test demonstrates the semiconductor property of the synthesized CuGaS2 polycrystalline thin film is p-type and the carrier concentration increases with negative shift of deposition potential. (C) 2014 The Electrochemical Society. All rights reserved.


¹Ø¼ü´Ê

KeyWords Plus:OPTICAL-PROPERTIES; CHOLINE CHLORIDE; GROWTH; MORPHOLOGY; SI(111)


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ͨѶ×÷ÕßµØÖ·: Niu, GH (ͨѶ×÷Õß)

Xiangtan Univ, Hunan Key Lab Micronano Energy Mat & Devices, Xiangtan 411105, Hunan, Peoples R China.




µØÖ·:  

[ 1 ] Xiangtan Univ, Hunan Key Lab Micronano Energy Mat & Devices, Xiangtan 411105, Hunan, Peoples R China


[ 2 ] Xiangtan Univ, Lab Quantum Engn & Micronano Energy Technol, Xiangtan 411105, Hunan, Peoples R China


[ 3 ] Xiangtan Univ, Fac Mat & Optoelect Phys, Xiangtan 411105, Hunan, Peoples R China


[ 4 ] Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China




µç×ÓÓʼþµØÖ·:syang@xtu.edu.cn


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»ù½ð×ÊÖú»ú¹¹

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National Nature Science Foundation  
51102203

51172191

51202208

National Basic Research Program of China  
2012CB921303

Open Fund based on the innovation platform of Hunan colleges and universities  
11K061

Hunan Provincial Natural Science Foundation of China  
10JJ2003

²é¿´»ù½ð×ÊÖúÐÅÏ¢   




³ö°æÉÌ

ELECTROCHEMICAL SOC INC, 65 SOUTH MAIN STREET, PENNINGTON, NJ 08534 USA


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Ñо¿·½Ïò:Electrochemistry; Materials Science

Web of Science Àà±ð:Electrochemistry; Materials Science, Coatings & Films


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ÎÄÏ×ÀàÐÍ:Article

ÓïÖÖ:English

Èë²ØºÅ: WOS:000339508600077

ISSN: 0013-4651

eISSN: 1945-7111


ÆÚ¿¯ÐÅÏ¢


Impact Factor (Ó°ÏìÒò×Ó):  Journal Citation Reports®


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IDS ºÅ: AM0BV

Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 32

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Liu, S. GROWTH, STRUCTURE AND OPTICAL CHARACTERIZATION OF CuGaS2 THIN FILMS OBTAINED BY SPRAY PYROLYSIS. CHALCOGENIDE LETTERS, MAR 2015.
2Â¥2015-04-27 15:02:51
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Preparation of Cu(In,Ga)S-2 Absorber Layers for Thin Film Solar Cell by Annealing of Electrodeposited Cu-Ga-S Precursor Layers  
×÷Õß:Yang, S (Yang, Sui)[ 1,2,3 ] ; Niu, GH (Niu, Guanghai)[ 1,2,3 ] ; Wang, MH (Wang, Minghao)[ 1,2,3 ] ; Li, MW (Li, Mingwei)[ 1,2,3 ] ; Li, HX (Li, Hongxing)[ 1,2,3 ] ; Yi, J (Yi, Jie)[ 4 ] ; Zhong, JX (Zhong, Jianxin)[ 1,2,3 ]  
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
¾í: 161

ÆÚ: 14

Ò³: D813-D819

DOI: 10.1149/2.0851414jes

³ö°æÄê: 2014

²é¿´ÆÚ¿¯ÐÅÏ¢


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Cu(In,Ga)S-2 (CIGS) thin film was synthesized on ITO glass substrate via electrodeposition of Cu-Ga-S precursor layer followed by thermal annealing treatment. Our results show that annealing temperature played an important role on the formation of CIGS crystallites. The pure quaternary chalcopyrite CIGS crystal phase in good crystallization with an uniform and compact surface morphology was reproducibly achieved after sintering at 400 degrees C. The metallic In atom diffused from the ITO substrate was found to incorporate to the Cu-Ga-S precursor film and allow the conversion of the quaternary chalcopyrite structure. Several characterization methods including X-ray diffraction (XRD), scanning electron microscope (SEM), energy diffraction spectrum (EDS) and high-resolution transmission electron microscopy (HRTEM) certified the incorporation of In. A possible growth mechanism for explaining the formation of CIGS thin films is proposed and briefly discussed. Completed CIGS solar cell device achieved a 5.75% total area power conversion efficiency under a simulated AM 1.5 illumination. (C) 2014 The Electrochemical Society. All rights reserved.


¹Ø¼ü´Ê

KeyWords Plus:ELECTRICAL-PROPERTIES; BAND-GAP; CUINS2; DEPOSITION; GROWTH; POLYCRYSTALLINE; NANOCRYSTALS; CRYSTALS


×÷ÕßÐÅÏ¢

ͨѶ×÷ÕßµØÖ·: Yang, S (ͨѶ×÷Õß)

Xiangtan Univ, Hunan Key Lab Micronano Energy Mat & Devices, Xiangtan 411105, Hunan, Peoples R China.

µØÖ·:  

[ 1 ] Xiangtan Univ, Hunan Key Lab Micronano Energy Mat & Devices, Xiangtan 411105, Hunan, Peoples R China


[ 2 ] Xiangtan Univ, Lab Quantum Engn & Micronano Energy Technol, Xiangtan 411105, Hunan, Peoples R China


[ 3 ] Xiangtan Univ, Fac Mat & Optoelect Phys, Xiangtan 411105, Hunan, Peoples R China


[ 4 ] Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China

µç×ÓÓʼþµØÖ·:syang@xtu.edu.cn


»ù½ð×ÊÖúÖÂл


»ù½ð×ÊÖú»ú¹¹

ÊÚȨºÅ

National Nature Science Foundation  
51102203

51172191

51202208

National Basic Research Program of China  
2012CB921303

Program for Changjiang Scholars and Innovative Research Team in University  
IRT13093

²é¿´»ù½ð×ÊÖúÐÅÏ¢   

³ö°æÉÌ

ELECTROCHEMICAL SOC INC, 65 SOUTH MAIN STREET, PENNINGTON, NJ 08534 USA


Àà±ð / ·ÖÀà

Ñо¿·½Ïò:Electrochemistry; Materials Science

Web of Science Àà±ð:Electrochemistry; Materials Science, Coatings & Films


ÎÄÏ×ÐÅÏ¢

ÎÄÏ×ÀàÐÍ:Article

ÓïÖÖ:English

Èë²ØºÅ: WOS:000345975500075

ISSN: 0013-4651

eISSN: 1945-7111


ÆÚ¿¯ÐÅÏ¢


Impact Factor (Ó°ÏìÒò×Ó):  Journal Citation Reports®


ÆäËûÐÅÏ¢

IDS ºÅ: AW0IO

Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 44

Web of Science ºËÐĺϼ¯ÖÐµÄ "±»ÒýƵ´Î": 0
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