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shaolin1120

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[求助] 关于缺陷浓度

The authors employ standard statistical model (i.e., canonical ensemble) to estimate defect concentration. However, when point defects appears and charge redistribution occurs, the standard Boltzmann statistical approach is not applicable especially for the system when charge transfer occurs between constituent elements (e.g., "40" structure on fcc lattice). This is because thermodynamic potential (such as internal energy or entropy) is no longer an extensive variable. Can the authors give description of how this non-extensively affects the present results based on charge transfer effects?
这是审稿人给的问题,但是我不明白什么意思,望各位指教!!
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