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雷焕银虫 (小有名气)
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[求助]
可能是什么物质。。。 已有1人参与
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急求！非常感谢大侠们 13C NMR (101 MHz, MeOD) δ 169.51 (s, 1H), 153.33 (s, 2H), 144.79 (s, 1H), 128.32 (s, 2H), 112.55 (s, 1H), 100.33 (s, 2H), 98.26 (s, 2H), 78.38 (s, 2H), 77.84 (s, 2H), 74.85 (s, 2H), 71.52 (s, 2H), 62.65 (s, 2H), 61.41 (s, 2H), 51.73 (s, 2H), 49.64 (s, 2H), 49.42 (s, 4H), 49.21 (s, 9H), 49.00 (s, 10H), 48.79 (s, 8H), 48.57 (s, 4H), 48.36 (s, 1H), 47.00 (s, 2H), 39.69 (s, 2H), 36.58 (s, 2H). 13C NMR (101 MHz, MeOD) δ 169.64 (s, 11H), 153.38 (s, 21H), 144.62 (s, 15H), 128.41 (s, 22H), 112.48 (s, 13H), 100.28 (s, 23H), 98.28 (s, 22H), 77.99 (d, J = 51.8 Hz, 47H), 74.76 (s, 23H), 71.42 (s, 24H), 62.55 (s, 23H), 61.34 (s, 23H), 51.85 (s, 20H), 50.22 – 50.04 (m, 1H), 49.96 (s, 8H), 49.90 – 49.42 (m, 41H), 49.21 (s, 42H), 49.12 (s, 5H), 49.00 (s, 41H), 48.68 (d, J = 21.4 Hz, 48H), 48.36 (s, 9H), 46.94 (s, 23H), 39.64 (s, 22H), 36.48 (s, 22H). 13C NMR (101 MHz, MeOD) δ 101.13 (s, 1H), 98.09 (s, 3H), 93.85 (s, 2H), 78.26 (s, 1H), 78.14 – 76.39 (m, 10H), 76.19 (s, 2H), 75.03 (s, 3H), 74.77 (s, 4H), 73.57 (d, J = 27.8 Hz, 5H), 72.92 (s, 2H), 71.71 (d, J = 11.7 Hz, 9H), 62.70 (d, J = 11.6 Hz, 8H), 55.49 (s, 1H), 49.74 (d, J = 21.0 Hz, 15H), 49.42 (s, 15H), 49.10 (d, J = 21.4 Hz, 71H), 48.82 (s, 4H), 48.82 (s, 4H), 48.82 (s, 9H), 48.81 – 48.07 (m, 55H). |
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雷焕: 金币+30, ★★★★★最佳答案, 非常感谢！ 2015-03-28 07:58:27
感谢参与，应助指数 +1
雷焕: 金币+30, ★★★★★最佳答案, 非常感谢！ 2015-03-28 07:58:27
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1111 1 . 10,6'-di-O-(1-methoxy-1-methylethyl)-geniposide C25H40O12 相似度:78.2% Journal of Natural Products 1999 62 1646-1654 Stereoselective Hydrogenation and Ozonolysis of Iridoids. Conversion into Carbocyclic Nucleoside Analogues Henrik Franzyk, and Frank R. Stermitz Structure 13C NMR 碳谱模拟图 2 . genameside C C23H34O15 相似度:73.9% Chemical & Pharmaceutical Bulletin 2005 53(10) 1342-1344 Iridoid Glucosides from the Fruit of Genipa americana Masateru ONO,Masami UENO,Chikako MASUOKA,Tsuyoshi IKEDA,and Toshihiro NOHARA Structure 13C NMR 碳谱模拟图 3 . genipin-gentiobioside 相似度:73.9% Chemical & Pharmaceutical Bulletin 2005 53(10) 1342-1344 Iridoid Glucosides from the Fruit of Genipa americana Masateru ONO,Masami UENO,Chikako MASUOKA,Tsuyoshi IKEDA,and Toshihiro NOHARA Structure 13C NMR 碳谱模拟图 4 . Genipin 1-O-β-D-isomaltoside C23H34O15 相似度:73.9% Phytochemistry 2009 70 779-784 Iridoid glycosides from Gardeniae Fructus for treatment of ankle sprain Quan Cheng Chen, Wei Yun Zhang, UiJoung Youn, HongJin Kim, IkSoo Lee, Hyun-Ju Jung, MinKyun Na, Byung-Sun Min, KiHwan Bae Structure 13C NMR 碳谱模拟图 5 . genipin 1-O-β-D-gentiobioside 相似度:73.9% Phytochemistry 2009 70 779-784 Iridoid glycosides from Gardeniae Fructus for treatment of ankle sprain Quan Cheng Chen, Wei Yun Zhang, UiJoung Youn, HongJin Kim, IkSoo Lee, Hyun-Ju Jung, MinKyun Na, Byung-Sun Min, KiHwan Bae Structure 13C NMR 碳谱模拟图 6 . genipin-1-O-β-D-gentiobioside 相似度:73.9% China Journal of Chinese Materia Medica 2009 34 1097-1100 A new flavonoid glucoside from Huanglian jiedutang decoction MA Zhaotang, YANG Xiuwei, ZHONG Guoyue Structure 13C NMR 碳谱模拟图 7 . genipin-gentiobioside 相似度:73.9% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR 碳谱模拟图 8 . genameside C 相似度:73.9% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR 碳谱模拟图 9 . genipin-1-gentiobioside 相似度:73.9% Lishizhen Medicine and Materia Medica Research 2013 24 1599-1603 黄连解毒汤化学成分及其神经细胞保护作用研究 杨阳, 赵海誉, 宋建芳, 王宏洁, 杨健, 司南, 刘庆山, 边宝林* Structure 13C NMR 碳谱模拟图 10 . genipin 1-O-β-D-apiofuranosyl(1→6)-β-D-glucopyranoside C22H32O14 相似度:69.5% Bioorganic & Medicinal Chemistry Letters 2013 23 1127-1131 Chemical constituents from the fruit of Gardenia jasminoides and their inhibitory effects on nitric oxide production Kaifeng Peng, Liguo Yang, Shizhe Zhao, Lixia Chen, Feng Zhao, Feng Qiu Structure 13C NMR 碳谱模拟图 222 1 . 10,6'-di-O-(1-methoxy-1-methylethyl)-geniposide C25H40O12 相似度:73.9% Journal of Natural Products 1999 62 1646-1654 Stereoselective Hydrogenation and Ozonolysis of Iridoids. Conversion into Carbocyclic Nucleoside Analogues Henrik Franzyk, and Frank R. Stermitz Structure 13C NMR 碳谱模拟图 2 . genameside C C23H34O15 相似度:69.5% Chemical & Pharmaceutical Bulletin 2005 53(10) 1342-1344 Iridoid Glucosides from the Fruit of Genipa americana Masateru ONO,Masami UENO,Chikako MASUOKA,Tsuyoshi IKEDA,and Toshihiro NOHARA Structure 13C NMR 碳谱模拟图 3 . genipin-gentiobioside 相似度:69.5% Chemical & Pharmaceutical Bulletin 2005 53(10) 1342-1344 Iridoid Glucosides from the Fruit of Genipa americana Masateru ONO,Masami UENO,Chikako MASUOKA,Tsuyoshi IKEDA,and Toshihiro NOHARA Structure 13C NMR 碳谱模拟图 4 . 2',3':4',6'-di-O-isopropylidene-geniposide C23H32O10 相似度:69.5% Journal of Natural Products 1999 62 1646-1654 Stereoselective Hydrogenation and Ozonolysis of Iridoids. Conversion into Carbocyclic Nucleoside Analogues Henrik Franzyk, and Frank R. Stermitz Structure 13C NMR 碳谱模拟图 5 . Genipin 1-O-β-D-isomaltoside C23H34O15 相似度:69.5% Phytochemistry 2009 70 779-784 Iridoid glycosides from Gardeniae Fructus for treatment of ankle sprain Quan Cheng Chen, Wei Yun Zhang, UiJoung Youn, HongJin Kim, IkSoo Lee, Hyun-Ju Jung, MinKyun Na, Byung-Sun Min, KiHwan Bae Structure 13C NMR 碳谱模拟图 6 . genipin-1-O-β-D-gentiobioside 相似度:69.5% China Journal of Chinese Materia Medica 2009 34 1097-1100 A new flavonoid glucoside from Huanglian jiedutang decoction MA Zhaotang, YANG Xiuwei, ZHONG Guoyue Structure 13C NMR 碳谱模拟图 7 . genipin 1-O-α-D-xylopyranosyl (1→6)-β-D-glucopyranoside C22H32O14 相似度:69.5% Bioorganic & Medicinal Chemistry Letters 2013 23 1127-1131 Chemical constituents from the fruit of Gardenia jasminoides and their inhibitory effects on nitric oxide production Kaifeng Peng, Liguo Yang, Shizhe Zhao, Lixia Chen, Feng Zhao, Feng Qiu Structure 13C NMR 碳谱模拟图 8 . genipin-gentiobioside 相似度:69.5% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR 碳谱模拟图 9 . genameside C 相似度:69.5% Chinese Traditional and Herbal Drugs 2014 45 16-22 Chemical constituents from root tubers of Rehmannia glutinosa LIU Yan-fei, LIANG Dong, LUO Huan, HAO Zhi-you, WANG Yan, ZHANG Chun-lei, CHEN Ruo-yun, YU De-quan Structure 13C NMR 碳谱模拟图 10 . genipin-1-gentiobioside 相似度:69.5% Lishizhen Medicine and Materia Medica Research 2013 24 1599-1603 黄连解毒汤化学成分及其神经细胞保护作用研究 杨阳, 赵海誉, 宋建芳, 王宏洁, 杨健, 司南, 刘庆山, 边宝林* Structure 13C NMR 碳谱模拟图 33 1 . maltose 相似度:63.1% Canadian Journal of Chemistry 1975 53 1030-1037 A Carbon-13 Nuclear Magnetic Resonance Study of Chlorinated and Polyol Analogs of Glucose and Related Oligomers Pierre Colson, Keith N. Slessor, H. J. Jennings, Ian C. P. Smith Structure 13C NMR 碳谱模拟图 2 . methyl gentiobioside 相似度:57.8% Chemical & Pharmaceutical Bulletin 1989 37 2727-2730 Two New Triterpenoid Glycosides from the Leaves of Schefflera octophylla Junichi KITAJIMA and Yasuko TANAKA Structure 13C NMR 碳谱模拟图 3 . K-red 相似度:57.8% Chemical & Pharmaceutical Bulletin 1982 30 4334-4340 Studies on the Constituents of Momordica charantia L. IV. Characterization of the New Cucurbitacin Glycosides of the Immature Fruits. (2) Structures of the Bitter Glycosides, Momordicosides K and L HIKARU OKABE,YUMI MIYAHARA and TATSUO YAMAUCHI Structure 13C NMR 碳谱模拟图 4 . ajureptaside C C16H26O10 相似度:57.8% Chemical & Pharmaceutical Bulletin 2011 59(8) 1065-1068 Four New Iridoid Glucosides from Ajuga reptans Masateru ONO, Chisato FURUSAWA,Takumi OZONO, Keisuke ODA, Shin YASUDA,Masafumi OKAWA, Junei KINJO, Tsuyoshi IKEDA, Hiroyuki MIYASHITA,Hitoshi YOSHIMITSU, and Toshihiro NOHARA Structure 13C NMR 碳谱模拟图 5 . β-D-吡喃葡萄糖基-(1→6)-β-D-吡喃葡萄糖基(1→4)2β2D2吡喃葡萄糖 相似度:57.8% Chinese Pharmaceutical Journal 2003 38 836-838 Studies on chemical constituents of Lysimachia davurica TIAN Jing kui, ZOU Zhong mei, XU Li zhen, Liu Jian xin, ZHANG Hong wu, YANG Shi lin Structure 13C NMR 碳谱模拟图 6 . 6'-chloro-6'-deoxymaltose 相似度:57.8% Canadian Journal of Chemistry 1975 53 1030-1037 A Carbon-13 Nuclear Magnetic Resonance Study of Chlorinated and Polyol Analogs of Glucose and Related Oligomers Pierre Colson, Keith N. Slessor, H. J. Jennings, Ian C. P. Smith Structure 13C NMR 碳谱模拟图 7 . compound 2 相似度:57.8% Magnetic Resonance in Chemistry 1997 35 414-419 1H and 13C NMR Data for 3-O-, 4-O- and 3,4-Di- 1O-glycosylated Methyl α-L-Rhamnopyranosides Elena A. Khatuntseva, Alexander S. Shashkov and Nikolay E. Nifant’ev Structure 13C NMR 碳谱模拟图 8 . N-Trisaccharide C12H33O15N 相似度:57.8% Phytomedicine 2014 21 624−630 Anti-diabetic effect of a novel N-Trisaccharide isolated from Cucumisprophetarum on streptozotocin–nicotinamide induced type 2 diabeticrats G.B. Kavishankar, N. Lakshmidevi Structure 13C NMR 碳谱模拟图 9 . tecomosid 相似度:52.6% Planta Medica 1985 51 229-232 Further Iridoid Glucosides from Penstemon strictus Peter Junior Structure 13C NMR 碳谱模拟图 10 . 3-epiphlomurin C18H28O11 相似度:52.6% Phytochemistry 2000 55 353-357 Iridoid and megastigmane glycosides from Phlomis aurea Mohamed S. Kamel, Khaled M. Mohamed, Hashim A. Hassanean, Kazuhiro Ohtani, Ryoji Kasai, Kazuo Yamasaki Structure 13C NMR 碳谱模拟图 |
2楼2015-03-27 23:03:35
