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武汉一心一译

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大四写论文: 金币+30, 翻译EPI+1, ★★★很有帮助 2015-03-20 15:53:27
Linkage of the cubes with shapes other than the linear ditopic linker can be described as the edge-transitive bimodal nets. If the D4R cages are regarded as cubelike vertices,connecting them through three-coordinate triangles, four-coordinate squares, four-coordinate tetrahedra, and eight-coordinate octahedra results in augmentation of the edge-transitive nets the; scu and sqc; flu; and ocu, respectively.

不同于线性异位链接器的形状的立方体,它连接处可看作是边缘传递双向网。如果D4R 笼被当作立方结构的顶点,通过三坐标三角形,四坐标方形,和四坐标四面体,八坐标八面体 调将它们连接在一起,从而增加边缘传递网.


Among them, the augmented form of the net (denoted the-a) is of particular interest to us because it has the lowest density,and rigid three-coordinate triangular molecules such as 3 are commercially available.
在它们中,我们对边缘传递网(记作-a)的扩充形态特别感兴趣。因为它密度最小,有最标准的三座标三角分子,例如三个都是市场上可买到的。


Considering the developed active catalysts, the scope and availability of reactants, the rigidity of the resulting bonds, and the need for inorganic and/or organic bases, we selected Sonogashira coupling from among Pd-catalyzed cross-coupling reactions.
对于成熟的活性催化剂,反应物的涉及的范围和有效性,化学键的硬度,以及对无机碱和/或有机碱的需求,我们从众多钯催化反应中,选择了薗头偶合反应。

The Sonogashira coupling reaction can be described as the reaction of terminal acetylenes with aryl or vinyl halides to produce internal alkynes (formation of carbon(sp)–carbonACHTUNGTRENUNG(sp2) bonds).
薗头偶合反应,被看作是终端乙炔与芳基或者乙烯基卤化物的反应,它可以生成内部炔烃(碳(sp)-碳ACHTUNGTRENUNG(sp2)键的形成)


注:; scu and sqc; flu; and ocu没有翻译,不知道是什么东东
2楼2015-03-20 14:36:53
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