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ÄÄλ´óÏÀÄܰïÎÒ²é²é»áÒéÂÛÎÄPolymerization of  N-Oxazoline Substituted Phenyl Methacrylamide with Large Optical ActivitiesÊÇ·ñ±»Ei¼ìË÷ÁË£¿Ð»Ð»¡£
·¢±íÓÚ¡¶WIT Transactions on Biomedicine and Health¡·(ISSN: 1743-3525) ÉÏ£¬(2014) Vol.19 pp.375-381
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Accession number:       
20144200114015
        Title:        Polymerization of N-oxazoline substituted phenyl methacrylamide with large optical activities
        Authors:        Li, Zhongwen1; Liu, Xiaomeng2; Yuan, Chao1; Fu, Zheng1
        Author affiliation:        1 Department of Pharmacy, Shandong Medical College, Jinan, China
                2 Archive, Shandong Medical College, Jinan, China
        Corresponding author:        Li, Zhongwen
        Source title:        WIT Transactions on Biomedicine and Health
        Abbreviated source title:        WIT Trans. Biomed. Health.
        Volume:        19
        Issue date:        2014
        Publication year:        2014
        Pages:        375-382
        Language:        English
        ISSN:        17433525
        ISBN-13:        9781845649920
        Document type:        Conference article (CA)
        Conference name:        2014 International Conference on Medical Engineering and Bioinformatics, MEB 2014
        Conference date:        April 7, 2014 - April 8, 2014
        Conference location:        Wuhan, China
        Conference code:        108115
        Sponsor:        Information Technology and Industrial Engineering Research Center
        Publisher:        WITPress
        Abstract:        Radical polymerization of chiral N-[o-(4-iso-Pr-4,5-dihydro-1,3-oxazol-2- yl)phenyl]methacrylamide ((S)-PriOPMAM) were carried out with AIBN or BPO initiator to obtained optical active polymers. The polymer yields and the chiroptical behavior of the resultant polymers have been examined in detail by using IR and1H NMR spectroscopies in comparison with our previous observation. The polymers showed relatively high molecular weights(Mn=6000¨C 14,000) and largest specific rotations([¦Á]25D =+187.6¡ã). Particularly, the largest specific optical rotation of the polymer is almost the two times of the monomer. © 2014 WIT Press.
        Number of references:        6
        Main heading:        Organic polymers
        Controlled terms:        Atom transfer radical polymerization  -  Bioinformatics  -  Biomedical engineering  -  Free radical polymerization  -  Manganese  -  Nitrogen compounds  -  Nuclear magnetic resonance spectroscopy  -  Optical materials  -  Polymerization
        Uncontrolled terms:        H NMR spectroscopy  -  High molecular weight  -  Methacrylamides  -  Optical active polymers  -  Optical activity  -  Oxazolines  -  Specific optical rotations  -  Specific rotations
        Classification code:        461.1 Biomedical Engineering -  543.2 Manganese and Alloys -  741.3 Optical Devices and Systems -  804.1 Organic Compounds -  815.1.1 Organic Polymers -  815.2 Polymerization -  903 Information Science -  932.2 Nuclear Physics
        DOI:        10.2495/MEB140481
        Database:        Compendex
                Compilation and indexing terms, © 2015 Elsevier Inc.
2Â¥2015-03-11 16:42:51
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