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Accession number: 20144200114015 Title: Polymerization of N-oxazoline substituted phenyl methacrylamide with large optical activities Authors: Li, Zhongwen1; Liu, Xiaomeng2; Yuan, Chao1; Fu, Zheng1 Author affiliation: 1 Department of Pharmacy, Shandong Medical College, Jinan, China 2 Archive, Shandong Medical College, Jinan, China Corresponding author: Li, Zhongwen Source title: WIT Transactions on Biomedicine and Health Abbreviated source title: WIT Trans. Biomed. Health. Volume: 19 Issue date: 2014 Publication year: 2014 Pages: 375-382 Language: English ISSN: 17433525 ISBN-13: 9781845649920 Document type: Conference article (CA) Conference name: 2014 International Conference on Medical Engineering and Bioinformatics, MEB 2014 Conference date: April 7, 2014 - April 8, 2014 Conference location: Wuhan, China Conference code: 108115 Sponsor: Information Technology and Industrial Engineering Research Center Publisher: WITPress Abstract: Radical polymerization of chiral N-[o-(4-iso-Pr-4,5-dihydro-1,3-oxazol-2- yl)phenyl]methacrylamide ((S)-PriOPMAM) were carried out with AIBN or BPO initiator to obtained optical active polymers. The polymer yields and the chiroptical behavior of the resultant polymers have been examined in detail by using IR and1H NMR spectroscopies in comparison with our previous observation. The polymers showed relatively high molecular weights(Mn=6000¨C 14,000) and largest specific rotations([¦Á]25D =+187.6¡ã). Particularly, the largest specific optical rotation of the polymer is almost the two times of the monomer. © 2014 WIT Press. Number of references: 6 Main heading: Organic polymers Controlled terms: Atom transfer radical polymerization - Bioinformatics - Biomedical engineering - Free radical polymerization - Manganese - Nitrogen compounds - Nuclear magnetic resonance spectroscopy - Optical materials - Polymerization Uncontrolled terms: H NMR spectroscopy - High molecular weight - Methacrylamides - Optical active polymers - Optical activity - Oxazolines - Specific optical rotations - Specific rotations Classification code: 461.1 Biomedical Engineering - 543.2 Manganese and Alloys - 741.3 Optical Devices and Systems - 804.1 Organic Compounds - 815.1.1 Organic Polymers - 815.2 Polymerization - 903 Information Science - 932.2 Nuclear Physics DOI: 10.2495/MEB140481 Database: Compendex Compilation and indexing terms, © 2015 Elsevier Inc. |
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