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Small最新综述:金属氧化物半导体在染料敏化与量子点太阳能电池中的应用
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本综述全面介绍了二氧化钛光电阳极染料敏化与量子点太阳能电池,金属氧化物替代二氧化钛染料敏化与量子点太阳能电池,其复合体系染料敏化与量子点太阳能电池 ,钙钛矿太阳能电池等,对染料敏化与量子点太阳能电池的研究添砖加瓦。 Metal Oxide Semiconductors for Dye- and Quantum-Dot-Sensitized Solar Cells 共31页 引文180篇 Isabella Concina* and Alberto Vomiero* Dr. I. Concina, Dr. A. Vomiero CNR-INO SENSOR Lab Via Branze 45, 25123 Brescia , Italy E-mail: isabella.concina@unibs.it; alberto.vomiero@ltu.se Dr. I. Concina University of Brescia Via Valotti 9, 25133 , Brescia , Italy Dr. A. Vomiero Luleå University of Technology 97198 , Luleå , Sweden This Review provides a brief summary of the most recent research developments in the synthesis and application of nanostructured metal oxide semiconductors for dye sensitized and quantum dot sensitized solar cells. In these devices, the wide bandgap semiconducting oxide acts as the photoanode, which provides the scaffold for light harvesters (either dye molecules or quantum dots) and electron collection. For this reason, proper tailoring of the optical and electronic properties of the photoanode can signifi cantly boost the functionalities of the operating device. Optimization of the functional properties relies with modulation of the shape and structure of the photoanode, as well as on application of different materials (TiO2, ZnO, SnO2) and/or composite systems, which allow fi ne tuning of electronic band structure. This aspect is critical because it determines exciton and charge dynamics in the photoelectrochemical system and is strictly connected to the photoconversion effi ciency of the solar cell. The different strategies for increasing light harvesting and charge collection, inhibiting charge losses due to recombination phenomena, are reviewed thoroughly, highlighting the benefi ts of proper photoanode preparation, and its crucial role in the development of high effi ciency dye sensitized and quantum dot sensitized solar cells. |
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2015-01-16 17:14:52, 8.06 M
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