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三生石5915

金虫 (正式写手)

[交流] 关于化学方法(类似于溶剂热方法)制备纳米粉体的一段话,请大家指教

最近看了一篇文献,对于里面一段解释想不清楚,请大家指教。
Herein, the TEG (HO(CH2CH2O)2CH2CH2OH) solvent has two hydroxy groups in each molecule. As we know, a hydroxy group will convert to an aldehyde group with donating two hydrogen atoms, which will successively release electrons to become H+ ions.
另外,次文献提到的方法:
a detached device was
self-designed in the solvothermal system as described previously[25], in which a tripod glass vessel was located into the Teflon-liner. In a typical synthesis, 0.293 g (1 mmol) of InCl3$4H2Owas dissolved in 5 mL of triethylene glycol (TEG) to be a clear solution under ultrasonic oscillation using an ordinary ultrasonic cleaner. The InCl3 solution of TEG was then transferred into the tripod glass vessel, in which the Cu foil coated with Cu(OH)2 film was immersed horizontally with the film side upward. Meanwhile, 0.376 g (5 mmol) of thioacetamide (TAA) was loaded into the Teflon-liner and dissolved in 15 mL TEG with stirring. The tripod glass vessel with Cu foil and InCl3 solution was then carefully deposited in autoclave. Hence, Cu foil and InCl3 solution could not be mixed with TAA solution.
是在反应釜里面放一个聚四氟乙烯衬底的玻璃皿吗?这个看不太懂。
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7楼2015-01-13 17:14:25
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三生石5915

金虫 (正式写手)

请高人来解答一下,有点不明白。
6楼2015-01-13 15:01:29
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