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1¡¢ÓÃÏ»®Ïß±êע˵Ã÷ÏÂÁи÷ÌâÖÐÿһ×ֶεĺ¬Òå¡£ £¨1£©ÆÚ¿¯³ö°æÎïµÄÎÄÕª±êÍ·£º 129£º248995z Calculation of the Hydrodynamic Contribution to Peak Asymmetry in High-Performance Liquid Chromatography Using the Eequilibrium-Dispersive Model. Stanley, Brett J.; Savag, Theresa L; Geraghty, Jennifer J. (Department of Chemistry Califonia State University, San Bernrdino, CA, 92407-2397, USA). Anal. Chem.. 1998,70(8), 1610-1617 (Eng), Americal Chemical Society. £¨2£©ÆÚ¿¯ÂÛÎÄÎÄժȫÎÄʾÀý£º 116£º105900k A new approach for the synthesis of the chiral sex pheromoneof peach leafminer moth.. Chen, Zikang; Zhu, Jun; Cheng, Ying (Dep. Chem., Beijing Norm. Univ., Beijing, Peop. Rep. China 100875). YoujiHuaxue 1991, 11(5), 530-3(Ch).The enantiomeric 14-methyl-1-octadecenes were prepd. by cross coupling reation between the Grignard reagent of 12-chloro-2-methylhexane from corresponding (R)-or (S)-2-methylhexanoic acid under the catalysis of Li2CuCl4. The overall yied of the each enantiomer is about 30% from the racemic 2-methylhexanoic acid and the optical purity is approx.100%. The (S)-enantiomer showed strong bioactivity as the sex pheromone of peach leafminer moth in field tests. |
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