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爱笑的阿里

木虫 (小有名气)

[求助] 英译汉(一段中的两句话)

nature某篇文章其中一段,帮忙翻译一下标红的地方,尽量精确点,前后文已经给出,非常感谢
Several anilines important for both organic synthesis and industry
are densely substituted with a variety of different functional
groups. Hence, for a generally applicable catalyst system it is essential
to perform the reduction of the nitro group highly chemoselectively.
Notably, such functional-group tolerance might also omit the
use of protecting groups and streamline more-complex syntheses.
Especially with respect to selectivity, the reduction of -NO2 in
the presence of other reducible substituents, such as ketones, aldehydes,
alkenes or alkynes, remains challenging
. Most
common commercially available Raney–nickel, palladium or platinum
catalysts are troubled by these issues. Nevertheless, Siegrist,
Blaser and co-workers achieved the selective reduction of substituted
nitroarenes using commercially available platinum catalysts
modified by special additives. More recently, another important
development came from the group of Corma, who disclosed a heterogeneous
gold-based catalyst that can hydrogenate nitro compounds
selectively in the presence of a number of functional
groups. Nevertheless, so far there exists no inexpensive nonnoble
metal catalyst system that allows for a general reduction of
all kinds of nitroarenes.
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ssssllllnnnn

至尊木虫 (知名作家)

Translator and Proofreader


【答案】应助回帖

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爱笑的阿里: 金币+50, 翻译EPI+1, ★★★★★最佳答案, 多谢大侠,多谢 2014-12-23 16:16:07
Notably, such functional-group tolerance might also omit the use of protecting groups and streamline more-complex syntheses. Especially with respect to selectivity, the reduction of -NO2 in the presence of other reducible substituents, such as ketones, aldehydes, alkenes or alkynes, remains challenging.

值得注意的是,这种官能团的耐受性也可能不用(或省略)使用保护基团,并简化更复杂的合成。尤其就选择性(而言),在酮、醛、烯烃或炔烃等其它可被还原取代基存在的条件下还原-NO2仍然具有挑战性。
4楼2014-12-22 22:31:31
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150465250

新虫 (小有名气)

【答案】应助回帖

★ ★ ★ ★ ★
爱笑的阿里: 金币+5, 谢谢,虽然没用,还是感谢 2014-12-23 16:16:47
需要指出的是,此功能群的容忍度也应该忽略保护群及更复杂流线合成的使用。特别是,对于选择性,在存在诸如酮、 醛、烯烃或炔属烃等其他还原剂的情况下,还原二氧化氮还有困难。
2楼2014-12-22 19:55:12
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爱笑的阿里

木虫 (小有名气)

引用回帖:
2楼: Originally posted by 150465250 at 2014-12-22 19:55:12
需要指出的是,此功能群的容忍度也应该忽略保护群及更复杂流线合成的使用。特别是,对于选择性,在存在诸如酮、 醛、烯烃或炔属烃等其他还原剂的情况下,还原二氧化氮还有困难。

这个翻译的不行啊,一点也不通顺啊
3楼2014-12-22 21:14:20
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