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[求助] 求助草酸锰。二水草酸猛的标准XRD衍射图谱谢谢！已有1人参与

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1楼2014-12-09 16:51:57

已阅关注TA 给TA发消息送TA红花 TA的回帖

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CMEI: 6
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专业: 催化化学

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Card Information
Names: alpha-Manganese Oxalate
Formula: C2 Mn O4
PDF Number: 32-646
Quality: unknown
Subfiles: inorganic organic CP  EDU

Cell and Symmetry Information
System: orthorhombic Space Group: Pmna    (no.  53)
a: 7.146 b: 5.878 c: 9.029
Density (Dx): 2.503 Z: 4

Instrument Information
Radiation: CuKa1 Wavelength: 1.5405
Instrument(d): unknown
Instrument(I): diffractometer I type: unknown

Comments and Additional Information
Pattern: To replace 00-014-0713.

Literature References
General: Huizing, A. et al. Mater. Res. Bull. 12 605 (1977)

Peak Data
Strong Lines: 5.83/X  5.57/6  3.55/5  2.76/3  2.78/3  4.89/3  2.67/2  2.30/2

PeakList
2-Theta d(?) I(f) ( h k l ) Theta 1/(2d) 2pi/d n^2
15.185 5.8300 100.0 ( 0 1 0) 7.592 0.0858 1.0777
15.898 5.5700 60.0 ( 1 0 1) 7.949 0.0898 1.1280
18.126 4.8900 25.0 ( 0 1 1) 9.063 0.1022 1.2849
19.712 4.5000 2.0 ( 0 0 2) 9.856 0.1111 1.3963
21.928 4.0500 3.0 ( 1 1 1) 10.964 0.1235 1.5514
25.063 3.5500 50.0 ( 2 0 0) 12.532 0.1408 1.7699
27.857 3.2000 1.0 ( 1 1 2) 13.929 0.1563 1.9635
30.505 2.9280 17.0 ( 0 2 0) 15.253 0.1708 2.1459
31.004 2.8820 2.0 ( 2 1 1) 15.502 0.1735 2.1801
32.184 2.7790 25.0 ( 0 2 1) 16.092 0.1799 2.2610
32.399 2.7610 30.0 ( 1 0 3) 16.200 0.1811 2.2757
33.536 2.6700 20.0 ( 0 1 3) 16.768 0.1873 2.3533
34.507 2.5970 1.0 ( 1 2 1) 17.254 0.1925 2.4194
35.802 2.5060 6.0 ( 1 1 3) 17.901 0.1995 2.5073
36.480 2.4610 2.0 ( 0 2 2) 18.240 0.2032 2.5531
38.765 2.3210 3.0 ( 1 2 2) 19.383 0.2154 2.7071
39.187 2.2970 20.0 ( 3 0 1) 19.593 0.2177 2.7354
39.984 2.2530 2.0 ( 0 0 4) 19.992 0.2219 2.7888
41.029 2.1980 2.0 ( 2 2 1) 20.515 0.2275 2.8586
42.173 2.1410 6.0 ( 2 1 3) 21.086 0.2335 2.9347
42.972 2.1030 2.0 ( 0 2 3) 21.486 0.2378 2.9877
44.949 2.0150 12.0 ( 1 2 3) 22.475 0.2481 3.1182
47.541 1.9110 7.0 ( 2 0 4) 23.771 0.2616 3.2879
48.789 1.8650 7.0 ( 3 0 3) 24.395 0.2681 3.3690
49.296 1.8470 2.0 ( 1 3 1) 24.648 0.2707 3.4018
50.255 1.8140 2.0 ( 2 1 4) 25.127 0.2756 3.4637
51.191 1.7830 5.0 ( 3 1 3) 25.595 0.2804 3.5239
52.422 1.7440 5.0 ( 1 3 2) 26.211 0.2867 3.6027
52.977 1.7270 4.0 ( 0 1 5) 26.489 0.2895 3.6382
53.750 1.7040 3.0 ( 4 1 0) 26.875 0.2934 3.6873
54.686 1.6770 3.0 ( 1 1 5) 27.343 0.2982 3.7467
58.518 1.5760 3.0 ( 3 2 3) 29.259 0.3173 3.9868
61.797 1.5000 2.0 ( 1 2 5) 30.899 0.3333 4.1888
64.326 1.4470 3.0 ( 4 2 2) 32.163 0.3455 4.3422
67.581 1.3850 1.0 ( 2 0 6) 33.791 0.3610 4.5366
69.818 1.3460 1.0 ( 2 4 1) 34.909 0.3715 4.6680

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2楼2014-12-10 08:47:28

已阅关注TA 给TA发消息送TA红花 TA的回帖

xhtangxh

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CMEI: 6
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红花: 107
帖子: 2676
在线: 599.3小时
虫号: 428580
注册: 2007-08-04
专业: 催化化学

【答案】应助回帖

Card Information
Names: Manganese Oxalate Hydrate
Formula: C2 Mn O4 !2 H2 O
PDF Number: 25-544
Quality: indexed
Subfiles: inorganic organic COR CP

Cell and Symmetry Information
System: monoclinic Space Group: C2/c    (no.  15)
a: 12.016 b: 5.632 c: 9.961
b: 128.4
Density (Dx): 2.250 Z: 4

Instrument Information
Radiation: Fe    Wavelength: 1.93604
Instrument(d): unknown
Instrument(I): diffractometer I type: unknown

Comments and Additional Information
Powder: CoKa=1.7902 is also used.
Pattern: To replace 00-014-0705.

Literature References
General: Deyrieux et al. Bull. Soc. Fr. Mineral. Cristallogr.       25 (1973)
Unit Cell: Ibid. Bull. Soc. Fr. Mineral. Cristallogr.          ( )

Peak Data
Strong Lines: 4.81/X  4.71/X  3.00/7  2.65/6  2.68/4  1.84/3  3.90/3  2.28/3

PeakList
2-Theta d(?) I(f) ( h k l ) Theta 1/(2d) 2pi/d n^2
18.164 4.8800 14.0 (-1 1 1) 9.082 0.1025 1.2875
18.430 4.8100 100.0 (-2 0 2) 9.215 0.1040 1.3063
18.825 4.7100 95.0 ( 2 0 0) 9.413 0.1062 1.3340
22.783 3.9000 30.0 ( 0 0 2) 11.391 0.1282 1.6111
24.299 3.6600 11.0 (-1 1 2) 12.149 0.1366 1.7167
24.502 3.6300 12.0 ( 1 1 1) 12.251 0.1377 1.7309
27.769 3.2100 2.0 (-3 1 2) 13.884 0.1558 1.9574
28.036 3.1800 7.0 (-3 1 1) 14.018 0.1572 1.9758
29.756 3.0000 70.0 (-4 0 2) 14.878 0.1667 2.0944
31.727 2.8180 13.0 ( 0 2 0) 15.863 0.1774 2.2297
33.458 2.6760 35.0 (-1 1 3) 16.729 0.1868 2.3480
33.757 2.6530 60.0 ( 1 1 2) 16.878 0.1885 2.3683
35.150 2.5510 2.0 (-2 2 1) 17.575 0.1960 2.4630
36.946 2.4310 6.0 (-2 2 2) 18.473 0.2057 2.5846
37.933 2.3700 3.0 ( 2 0 2) 18.966 0.2110 2.6511
38.200 2.3540 1.0 ( 4 0 0) 19.100 0.2124 2.6692
39.419 2.2840 25.0 ( 0 2 2) 19.709 0.2189 2.7510
40.301 2.2360 6.0 ( 3 1 1) 20.151 0.2236 2.8100
41.107 2.1940 4.0 (-5 1 3) 20.554 0.2279 2.8638
41.344 2.1820 1.0 (-5 1 2) 20.672 0.2291 2.8796
42.090 2.1450 10.0 (-2 2 3) 21.045 0.2331 2.9292
42.485 2.1260 10.0 ( 2 2 1) 21.242 0.2352 2.9554
44.050 2.0540 7.0 (-4 2 2) 22.025 0.2434 3.0590
44.438 2.0370 18.0 ( 1 1 3) 22.219 0.2455 3.0845
44.832 2.0200 9.0 (-5 1 1) 22.416 0.2475 3.1105
45.473 1.9930 4.0 (-4 2 3) 22.736 0.2509 3.1526
45.813 1.9790 3.0 (-4 2 1) 22.906 0.2527 3.1749
46.483 1.9520 17.0 ( 0 0 4) 23.242 0.2561 3.2188
47.071 1.9290 12.0 (-6 0 2) 23.535 0.2592 3.2572
47.331 1.9190 16.0 ( 0 2 3) 23.666 0.2606 3.2742
48.985 1.8580 4.0 (-3 1 5) 24.493 0.2691 3.3817
49.410 1.8430 30.0 (-1 3 1) 24.705 0.2713 3.4092
49.814 1.8290 18.0 (-4 2 4) 24.907 0.2734 3.4353
50.284 1.8130 6.0 ( 2 2 2) 25.142 0.2758 3.4656
51.099 1.7860 2.0 ( 5 1 0) 25.549 0.2800 3.5180
52.260 1.7490 5.0 (-1 3 2) 26.130 0.2859 3.5924
54.162 1.6920 4.0 (-3 3 2) 27.081 0.2955 3.7135
55.658 1.6500 6.0 (-1 1 5) 27.829 0.3030 3.8080
56.102 1.6380 10.0 ( 1 1 4) 28.051 0.3053 3.8359
57.478 1.6020 11.0 (-6 2 4) 28.739 0.3121 3.9221
57.874 1.5920 5.0 ( 1 3 2) 28.937 0.3141 3.9467
59.303 1.5570 8.0 (-2 2 5) 29.651 0.3211 4.0354
59.429 1.5540 1.0 ( 5 1 1) 29.714 0.3218 4.0432
60.897 1.5200 2.0 ( 3 1 3) 30.448 0.3289 4.1337
61.119 1.5150 6.0 (-6 2 5) 30.560 0.3300 4.1473

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3楼2014-12-10 08:49:33

已阅关注TA 给TA发消息送TA红花 TA的回帖

xhtangxh

木虫 (著名写手)

有木有虫

CMEI: 6
应助: 773 (博后)
金币: 17832.4
红花: 107
帖子: 2676
在线: 599.3小时
虫号: 428580
注册: 2007-08-04
专业: 催化化学

【答案】应助回帖

★ ★ ★ ★ ★
wyf_fu: 金币+5, ★★★★★最佳答案, 给力 2014-12-10 11:04:05

Card Information
Names: Manganese Oxalate Hydrate
Formula: C2 Mn O4 !2 H2 O
PDF Number: 32-647
Quality: unknown
Subfiles: inorganic organic COR

Cell and Symmetry Information
System: orthorhombic Space Group: P212121  (no.  19)
a: 6.265 b: 6.086 c: 13.59
Density (Dx): 2.294 Z: 4

Instrument Information
Radiation: CuKa1 Wavelength: 1.5405
Instrument(d): unknown
Instrument(I): diffractometer I type: unknown

Comments and Additional Information
d-Spacings: 1 Intensity very high, probably due to preferred orientation.

Literature References
General: Huizinga, A. et al. Mater. Res. Bull. 12 605 (1977)

Peak Data
Strong Lines: 5.65/X  3.04/5  1.98/1  2.84/1

PeakList
2-Theta d(?) I(f) ( h k l ) Theta 1/(2d) 2pi/d n^2
13.086 6.7600 1.0 ( 0 0 2) 6.543 0.0740 0.9295
15.671 5.6500 100.0 ( 1 0 1) 7.836 0.0885 1.1121
19.322 4.5900 3.0 ( 1 0 2) 9.661 0.1089 1.3689
19.624 4.5200 1.0 ( 0 1 2) 9.812 0.1106 1.3901
20.399 4.3500 1.0 ( 1 1 0) 10.199 0.1149 1.4444
21.393 4.1500 1.0 ( 1 1 1) 10.697 0.1205 1.5140
24.299 3.6600 3.0 ( 1 0 3) 12.149 0.1366 1.7167
24.571 3.6200 3.0 ( 0 1 3) 12.286 0.1381 1.7357
26.267 3.3900 1.0 ( 0 0 4) 13.134 0.1475 1.8534
28.493 3.1300 4.0 ( 2 0 0) 14.247 0.1597 2.0074
29.355 3.0400 50.0 ( 0 2 0) 14.678 0.1645 2.0668
30.022 2.9740 1.0 ( 0 2 1) 15.011 0.1681 2.1127
31.520 2.8360 6.0 ( 2 0 2) 15.760 0.1763 2.2155
32.196 2.7780 1.0 ( 0 2 2) 16.098 0.1800 2.2618
32.765 2.7310 1.0 ( 2 1 1) 16.383 0.1831 2.3007
33.484 2.6740 2.0 ( 1 1 4) 16.742 0.1870 2.3497
34.882 2.5700 3.0 ( 2 0 3) 17.441 0.1946 2.4448
35.365 2.5360 3.0 ( 1 2 2) 17.682 0.1972 2.4776
36.055 2.4890 2.0 ( 1 0 5) 18.028 0.2009 2.5244
37.983 2.3670 1.0 ( 2 1 3) 18.991 0.2112 2.6545
38.438 2.3400 1.0 ( 1 2 3) 19.219 0.2137 2.6851
39.080 2.3030 2.0 ( 2 0 4) 19.540 0.2171 2.7283
39.818 2.2620 1.0 ( 0 0 6) 19.909 0.2210 2.7777
41.383 2.1800 2.0 ( 2 2 0) 20.692 0.2294 2.8822
41.988 2.1500 2.0 ( 2 1 4) 20.994 0.2326 2.9224
42.422 2.1290 1.0 ( 1 0 6) 21.211 0.2349 2.9512
42.548 2.1230 1.0 ( 0 1 6) 21.274 0.2355 2.9596
43.582 2.0750 1.0 ( 2 2 2) 21.791 0.2410 3.0280
43.893 2.0610 3.0 ( 3 0 1) 21.947 0.2426 3.0486
44.738 2.0240 1.0 ( 0 2 5) 22.369 0.2470 3.1043
45.740 1.9820 9.0 ( 3 1 0) 22.870 0.2523 3.1701
45.960 1.9730 1.0 ( 2 2 3) 22.980 0.2534 3.1846
46.483 1.9520 2.0 ( 3 1 1) 23.242 0.2561 3.2188
47.123 1.9270 1.0 ( 1 2 5) 23.561 0.2595 3.2606
47.968 1.8950 1.0 ( 3 0 3) 23.984 0.2639 3.3157
49.154 1.8520 1.0 ( 0 3 3) 24.577 0.2700 3.3926
49.669 1.8340 1.0 ( 2 0 6) 24.835 0.2726 3.4259
50.403 1.8090 1.0 ( 3 1 3) 25.202 0.2764 3.4733
51.376 1.7770 2.0 ( 1 3 3) 25.688 0.2814 3.5358
52.036 1.7560 1.0 ( 2 1 6) 26.018 0.2847 3.5781
52.196 1.7510 1.0 ( 1 2 6) 26.098 0.2856 3.5883
53.682 1.7060 1.0 ( 3 1 4) 26.841 0.2931 3.6830
54.266 1.6890 1.0 ( 2 3 1) 27.133 0.2960 3.7201
55.006 1.6680 1.0 ( 3 2 2) 27.503 0.2998 3.7669
55.585 1.6520 1.0 ( 2 3 2) 27.793 0.3027 3.8034
56.214 1.6350 1.0 ( 0 1 8) 28.107 0.3058 3.8429
57.205 1.6090 1.0 ( 3 2 3) 28.603 0.3108 3.9050
57.715 1.5960 1.0 ( 3 1 5) 28.857 0.3133 3.9368
57.913 1.5910 1.0 ( 2 1 7) 28.957 0.3143 3.9492
58.274 1.5820 1.0 ( 1 1 8) 29.137 0.3161 3.9717
58.722 1.5710 1.0 ( 2 2 6) 29.361 0.3183 3.9995
58.928 1.5660 1.0 ( 4 0 0) 29.464 0.3193 4.0123
59.429 1.5540 1.0 ( 4 0 1) 29.714 0.3218 4.0432
60.283 1.5340 1.0 ( 3 0 6) 30.142 0.3259 4.0959
60.808 1.5220 1.0 ( 2 3 4) 30.404 0.3285 4.1282
61.030 1.5170 1.0 ( 4 1 0) 30.515 0.3296 4.1418
61.524 1.5060 1.0 ( 4 1 1) 30.762 0.3320 4.1721
62.212 1.4910 1.0 ( 2 0 8) 31.106 0.3353 4.2141
62.351 1.4880 1.0 ( 3 1 6) 31.176 0.3360 4.2226
62.773 1.4790 2.0 ( 1 4 0) 31.387 0.3381 4.2483
63.979 1.4540 1.0 ( 3 2 5) 31.990 0.3439 4.3213
64.177 1.4500 1.0 ( 2 1 8) 32.088 0.3448 4.3332
64.526 1.4430 1.0 ( 2 3 5) 32.263 0.3465 4.3543
64.777 1.4380 1.0 ( 4 1 3) 32.389 0.3477 4.3694
65.442 1.4250 1.0 ( 1 1 9) 32.721 0.3509 4.4093
65.597 1.4220 1.0 ( 3 0 7) 32.799 0.3516 4.4186
67.637 1.3840 1.0 ( 3 1 7) 33.818 0.3613 4.5399
69.229 1.3560 1.0 ( 1 4 4) 34.615 0.3687 4.6336
70.176 1.3400 1.0 ( 2 2 8) 35.088 0.3731 4.6889
70.783 1.3300 1.0 ( 4 2 3) 35.391 0.3759 4.7242
71.028 1.3260 1.0 ( 0 1 10) 35.514 0.3771 4.7385
71.152 1.3240 1.0 ( 4 1 5) 35.576 0.3776 4.7456
72.868 1.2970 1.0 ( 1 1 10) 36.434 0.3855 4.8444
73.460 1.2880 1.0 ( 3 1 8) 36.730 0.3882 4.8783
75.372 1.2600 1.0 ( 4 1 6) 37.686 0.3968 4.9867
76.298 1.2470 1.0 ( 2 0 10) 38.149 0.4010 5.0386
76.880 1.2390 1.0 ( 4 2 5) 38.440 0.4036 5.0712
77.472 1.2310 1.0 ( 5 0 2) 38.736 0.4062 5.1041
78.151 1.2220 1.0 ( 5 1 1) 39.075 0.4092 5.1417
79.312 1.2070 1.0 ( 5 0 3) 39.656 0.4143 5.2056
80.269 1.1950 1.0 ( 1 5 0) 40.135 0.4184 5.2579
80.922 1.1870 1.0 ( 3 4 3) 40.461 0.4212 5.2933
81.924 1.1750 1.0 ( 0 5 3) 40.962 0.4255 5.3474
83.747 1.1540 1.0 ( 5 1 4) 41.873 0.4333 5.4447
84.831 1.1420 1.0 ( 5 2 2) 42.415 0.4378 5.5019
85.853 1.1310 1.0 ( 2 5 1) 42.927 0.4421 5.5554
86.137 1.1280 1.0 ( 4 3 5) 43.069 0.4433 5.5702
87.099 1.1180 1.0 ( 5 1 5) 43.549 0.4472 5.6200

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4楼2014-12-10 08:51:27

已阅关注TA 给TA发消息送TA红花 TA的回帖

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[求助] 求助草酸锰。二水草酸猛的标准XRD衍射图谱 谢谢！已有1人参与

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xhtangxh

【答案】应助回帖

xhtangxh

【答案】应助回帖

xhtangxh

【答案】应助回帖

[求助] 求助草酸锰。二水草酸猛的标准XRD衍射图谱谢谢！已有1人参与