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[资源] 晶体材料热分析（微晶、纳米晶体及非晶体）：转变-结晶-动力学及热力学（英文版）

Thermal analysis of Micro, Nano- and Non-Crystalline Materials: Transformation, Crystallization, Kinetics and Thermodynamics

Thermal Analysis of Micro-, Nano- and Non-Crystalline Materials: Transformation, Crystallization, Kinetics and Thermodynamics complements and adds to volume 8 Glassy, Amorphous and Nano-Crystalline Materials by providing a coherent and authoritative overview of cutting-edge themes in the field of crystalline materials. In particular, the book focuses on reaction thermodynamics and kinetics applied to solid-state chemistry and thermal physics of various states of materials.
In this volume the fundamental and historical aspects of phenomenological kinetics and the equilibrium background of processes are detailed. Crystal defects, non-stoichiometry and nano-crystallinity, reduced glass-transition temperatures and glass-forming coefficients are covered. The determination of the glass transition by DSC, the role of heat transfer and phase transition in DTA experiments, and the explanation of DTA/DSC methods used for the estimation of crystal nucleation are reviewed. Structural relaxation and viscosity behaviour in glass and associated relaxation kinetics are also examined, together with the influence of preliminary nucleation and coupled phenomenological kinetics nucleation on both the strongly curved surfaces and nano-particles. The book investigates crystallization of glassy and amorphous materials including oxides, chalcogenides and metals, non-parametric and fractal description of kinetics, disorder and dimensionality in nano-crystalline diamond. Moreover, it analyzes thermal analysis of waste glass batches, amorphous inorganic polysialates and bioactivity of hydroxyl groups as well as reaction kinetics and unconventional glass formability of oxide superconductors.
Written by an international array of distinguished academics, Thermal Analysis of Micro-, Nano- and Non-Crystalline Materials: Transformation, Crystallization, Kinetics and Thermodynamics is a valuable resource to advanced undergraduates, postgraduates, and researches working in the fields of applied material thermodynamics, thermal analysis, thermophysical measurements and calorimetry.
Table of contents :
Content:
Front Matter....Pages i-xxi
Some Fundamental and Historical Aspects of Phenomenological Kinetics in the Solid State Studied by Thermal Analysis....Pages 1-28
Equilibrium Background of Processes Initiated by Heating and Ehrenfest’s Classification of Phase Transitions....Pages 29-51
Crystal Defects and Nonstoichiometry Contributions to Heat Capacity of Solids....Pages 53-74
Forty Years of the Turnbull Reduced Glass Transition Temperature and Hrub? Glass-Forming Coefficient and Their Current Perception....Pages 75-97
Heat Transfer and Phase Transition in DTA Experiments....Pages 99-133
Determination of the Glass Transition by DSC: A Comparison of Conventional and Dynamic Techniques....Pages 135-146
Structural Relaxation and Viscosity Behavior in Supercooled Liquids at the Glass Transition....Pages 147-173
Kinetics of Structural Relaxation in Glasses....Pages 175-194
Kinetics of Crystal Nucleation in Closed Systems....Pages 195-208
Influence of Preliminary Nucleation on the Physicogeometric Kinetics of Glass Crystallization....Pages 209-223
Application of Isoconversional Methods for the Processes Occurring in Glassy and Amorphous Materials....Pages 225-246
Fractals in Solid-State Processes....Pages 247-255
Crystallization of Metallic Micro-, Nano-, and Non-Crystalline Alloys....Pages 257-289
Crystallization Kinetics in Amorphous and Glassy Materials....Pages 291-324
Comments on DTA/DSC Methods for Estimation of Crystal Nucleation Rates in Glass-Forming Melts....Pages 325-350
Nonparametric Kinetic Methods....Pages 351-369
Electron Transport Studies of Disorder and Dimensionality in Nano-Crystalline Diamond....Pages 371-397
Controlled Nucleation and Crystallization for Nanoparticle Synthesis....Pages 399-418
Nucleation on Strongly Curved Surfaces of Nanofibers....Pages 419-428
Thermal Analysis of Waste Glass Batches: Effect of Batch Makeup on Gas-Evolving Reactions....Pages 429-440
Amorphous Inorganic Polysialates: Geopolymeric Composites and the Bioactivity of Hydroxyl Groups....Pages 441-460
Oxide Superconductors as Model Systems for Studying Phase Relations, Stoichiometry, Reaction Kinetics, and Unconventional Glass Formability....Pages 461-480
Back Matter....Pages 481-484

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2014-12-06 14:45:08, 8.03 M