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Chem Soc Rev热点综述：石墨烯基宏观装配和结构
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Graphene-based macroscopic assemblies and architectures: an emerging material system共32页 引文331篇 Huai-Ping Cong,*ab Jia-Fu Chena and Shu-Hong Yu*a a Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. b Anhui Key Laboratory of Controllable Chemical Reaction and Material Chemical Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui 230009, P. R. China. Due to the outstanding physicochemical properties arising from its truly two-dimensional (2D) planar structure with a single-atom thickness, graphene exhibits great potential for use in sensors, catalysts, electrodes, and in biological applications, etc. With further developments in the theoretical understanding and assembly techniques, graphene should enable great changes both in scientific research and practical industrial applications. By the look of development, it is of fundamental and practical significance to translate the novel physical and chemical properties of individual graphene nanosheets into the macroscale by the assembly of graphene building blocks into macroscopic architectures with structural specialities and functional novelties. The combined features of a 2D planar structure and abundant functional groups of graphene oxide (GO) should provide great possibilities for the assembly of GO nanosheets into macroscopic architectures with different macroscaled shapes through various assembly techniques under different bonding interactions. Moreover, macroscopic graphene frameworks can be used as ideal scaffolds for the incorporation of functional materials to offset the shortage of pure graphene in the specific desired functionality. The advantages of light weight, supra-flexibility, large surface area, tough mechanical strength, and high electrical conductivity guarantee graphene-based architectures wide application fields. This critical review mainly addresses recent advances in the design and fabrication of graphene-based macroscopic assemblies and architectures and their potential applications. Herein, we first provide overviews of the functional macroscopic graphene materials from three aspects, i.e., 1D graphene fibers/ribbons, 2D graphene films/papers, 3D network-structured graphene monoliths, and their composite counterparts with either polymers or nano-objects. Then, we present the promising potential applications of graphene-based macroscopic assemblies in the fields of electronic and optoelectronic devices, sensors, electrochemical energy devices, and in water treatment. Last, the personal conclusions and perspectives for this intriguing field are given.请小伙伴们下载后给个好评！  5.jpg |
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2014-11-13 01:10:16, 10.25 M
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thank you 29楼2014-11-15 02:03:58
11楼2014-11-13 10:55:53
简单回复
2014-11-13 06:35
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五星好评 顶一下，感谢分享！
朱十三3楼
2014-11-13 07:49
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五星好评 顶一下，感谢分享！
2014-11-13 08:29
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五星好评 顶一下，感谢分享！
2014-11-13 09:09
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五星好评 顶一下，感谢分享！
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2014-11-13 09:27
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五星好评 顶一下，感谢分享！
2014-11-13 09:42
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五星好评 顶一下，感谢分享！
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2014-11-13 10:01
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五星好评 顶一下，感谢分享！
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2014-11-13 10:27
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五星好评 顶一下，感谢分享！
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2014-11-13 10:54
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五星好评 
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2014-11-13 14:47
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2014-11-13 16:19
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2014-11-13 16:26
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五星好评 顶一下，感谢分享！
