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Ç×°®µÄ¸÷λ³æÓÑÃÇ£¬¿ÆÑеÀ·ÉϵÄͬ°éÃÇ£¬ÄãÃǺã¡ ²»ÂÛÄãÊǸոսӴ¥Ñ§ÊõµÄ²ËÄñ£¬»¹ÊÇÔÚ¿ÆÑÐÁìÓòÆÄÓÐÐĵõÄÀϱø£¬Ò²¿ÉÄÜÒѾÊÇijһѧ¿ÆµÄѧÊõ´øÍ·ÈË£¬ÏëÀ´¶¼¶ÔÎÄÏ××ÛÊö²¢²»Ä°Éú¡£ µ±ÎÒÃdzõ³ö鮵Äʱºò£¬Ò»Æª×ÛÊö¿ÉÄÜ»áÈÃÎÒÃÇÀíÇåѧ¿Æ¹ýÈ¥µÄ·¢Õ¹ÀúÊ·£¬Á˽âÏÖ½ñµÄÑо¿×´¿ö£¬²¢Äܹ»°ÑÎÕѧ¿ÆÎ´À´µÄÑо¿×ßÏò¡¢Öص㼰Èȵ㡣 10Äê¡¢20Äê¡¢ÉõÖÁ100ÄêµÄʱ¼ä¿ç¶È£¬ÓÉǰ±²´øÄãÒ»Ò»×ß¹ý£¬·á¸»µÄѧÊõ֪ʶ¡¢ÐÅÏ¢ºÍϸ½Ú£¬¶¼¿ÉÒÔʹÎÒÃÇ´ÓÖлñÈ¡×ã¹»µÄѧÊõÑø·Ö¡£ Òò´Ë£¬Ñо¿×ÛÊö£¬Ó¦µ±ÊÇÒ»¸ö¿ÆÑвËÄñ´ÓÊÂѧÊõÑо¿µÄµÚÒ»¿Î£¬Ò²ÊÇ×ÅÊÖÑо¿µÄ±Ø±¸¶ÁÎï¡£ ±¾´Î»î¶¯ÃæÏò¸÷λ³æÓÑ£¬»¶Ó½«Äú¿´¹ýµÄÎÄÏ××ÛÊöÓë´ó¼Ò·ÖÏí£¬Îª¿ÆÑзÉϵÄÐÂÈË·ÅÏÂÒ»×ùµÆËþ¡£ ÎÒÃǽ«°´×ÛÊöµÄÖÊÁ¿ºÍÊýÁ¿·¢·Å½±Àø¡£ ²ÎÓë»ØÌû²Î¿¼¸ñʽÈçÏ£¬Ò²»¶Ó¸÷λÌá³ö±¦¹óµÄ½¨Òé¡£ Ò²¿ÉÒÔ½«ÎļþÁíÌù·¢²¼µ½¹¦ÄܲÄÁϰ棬ÔÚ´ËÌûÁôÏÂÁ´½Ó£¬¶Ô·ûºÏÒªÇóµÄ¿ÉÒÔ¼ÓÒÔ¾«»ª¡£ ¡¾Ïà¹ØÁìÓò¡¿ ³ÚÔ¥Ìúµçµ¥¾§ ¡¾×÷Õß¡¿ Enwei Sun, Wenwu Cao ¡¾ÌâÄ¿¡¿ Relaxor-based ferroelectric single crystals: growth, domain engineering, characterization and applications ¡¾¿¯Ãû¡¿ Progress in Materials Science ¡¾³ö°æÈÕÆÚ¡¿ August 2014 ¡¾¾íÆÚºÅ¡¿ Volume 65 ¡¾Ò³Âë¡¿ Pages 124¨C210 ¡¾ÕªÒª¡¿ In the past decade, domain engineered relaxor-PT ferroelectric single crystals, including (1 x)Pb(Mg1/3Nb2/3)O3¨CxPbTiO3 (PMN¨CPT), (1 x)Pb(Zn1/3Nb2/3)O3¨CxPbTiO3 (PZN¨CPT) and (1 x y)Pb(In1/2Nb1/2)O3¨CyPb(Mg1/3Nb2/3)O3¨CxPbTiO3 (PIN¨CPMN¨CPT), with compositions near the morphotropic phase boundary (MPB) have triggered a revolution in electromechanical devices owing to their giant piezoelectric properties and ultra-high electromechanical coupling factors. Compared to traditional PbZr1³`…¸—µí¸?«3 (PZT) ceramics, the piezoelectric coefficient d33 is increased by a factor of 5 and the electromechanical coupling factor k33 is increased from <70% to >90%. Many emerging rich physical phenomena, such as charged domain walls, multi-phase coexistence, and domain pattern symmetries, have posed challenging fundamental questions for scientists. The superior electromechanical properties of these domain engineered single crystals have prompted the design of a new generation electromechanical devices, including sensors, transducers, actuators and other electromechanical devices, with greatly improved performance. It took less than 7 years from the discovery of larger size PMN¨CPT single crystals to the commercial production of the high-end ultrasonic imaging probe ¡°PureWave¡±. The speed of development is unprecedented, and the research collaboration between academia and industrial engineers on this topic is truly intriguing. It is also exciting to see that these relaxor-PT single crystals are being used to replace traditional PZT piezoceramics in many new fields outside of medical imaging. The new ternary PIN¨CPMN¨CPT single crystals, particularly the ones with Mn-doping, have laid a solid foundation for innovations in high power acoustic projectors and ultrasonic motors, hinting another revolution in underwater SONARs and miniature actuation devices. This article intends to provide a comprehensive review on the development of relaxor-PT single crystals, spanning material discovery, crystal growth techniques, domain engineering concept, and full-matrix property characterization all the way to device innovations. It outlines a truly encouraging story in materials science in the modern era. All key references are provided and 30 complete sets of material parameters for different types of relaxor-PT single crystals are listed in Appendix A. It is the intension of this review article to serve as a resource for those who are interested in basic research and practical applications of these relaxor-PT single crystals. In addition, possible mechanisms of giant piezoelectric properties in these domain-engineered relaxor-PT systems will be discussed based on contributions from polarization rotation and charged domain walls. [ Last edited by ivansdk on 2014-10-28 at 22:43 ] |
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