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赖旭

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文章标题:Structure and properties of gadolinium loaded calcium phosphate glasses
作者:Cuiling Wang, Xiaofeng Liang, Haijian Li, Huijun Yua, Zhen Li, Shiyuan Yang
单位:a Analytical and Testing Center, Southwest University of Science and Technology, Mianyang 621010, PR China
b State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, PR China
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赖旭: 金币+5, ★★★★★最佳答案, 谢谢 2014-10-20 15:02:46
oven1986: LS-EPI+1, 感谢应助! 2014-10-20 15:09:19
入藏号: WOS:000341679900031
4楼2014-10-20 14:39:28
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Structure and properties of gadolinium loaded calcium phosphate glasses


作者:Wang, CL (Wang, Cuiling)[ 1,2 ] ; Liang, XF (Liang, Xiaofeng)[ 1,2 ] ; Li, HJ (Li, Haijian)[ 1,2 ] ; Yu, HJ (Yu, Huijun)[ 1,2 ] ; Li, Z (Li, Zhen)[ 1,2 ] ; Yang, SY (Yang, Shiyuan)[ 1,2 ]




JOURNAL OF NUCLEAR MATERIALS



卷: 453

期: 1-3

页: 220-224

DOI: 10.1016/j.jnucmat.2014.06.034

出版年: OCT 2014

查看期刊信息












































摘要

The glass samples with composition xGd(2)O(3)-(50 - x)CaO-50P(2)O(5) (0 <= x <= 9 mol%) were prepared by the conventional melt quench method. The structure and properties of gadolinium loaded in calcium phosphate glasses were investigated using XRD, SEM, DTA, IR and Raman spectroscopy. The XRD and SEM analysis for the samples show that the majority of samples are amorphous, and crystallization occurs when the content of Gd2O3 containing is up to 6 mol%. Two main crystalline phases, Ca2P2O7 and Gd-3(P2O7)(3), are embedded in an amorphous matrix. IR and Raman data indicate that glass structure consists of predominantly metaphosphate (Q(2)) units and the depolymerization of phosphate network with the addition of Gd2O3. Both the chemical durability and the glass transition temperature (T-g) are improved with the increase of Gd2O3, which suggests that the Gd acts a role of strengthening the cross-links between the phosphate chains of the glass. (C) 2014 Elsevier B.V. All rights reserved.


关键词

KeyWords Plus:SODIUM ULTRAPHOSPHATE GLASSES; RAMAN-SPECTROSCOPY; RADIOACTIVE-WASTES; INFRARED-SPECTRA; IN-VITRO; CRYSTALLIZATION; IMMOBILIZATION; METAL


作者信息

通讯作者地址: Liang, XF (通讯作者)





Southwest Univ Sci & Technol, Analyt & Testing Ctr, Mianyang 621010, Peoples R China.





地址:





[ 1 ] Southwest Univ Sci & Technol, Analyt & Testing Ctr, Mianyang 621010, Peoples R China







[ 2 ] Southwest Univ Sci & Technol, State Key Lab Cultivat Base Nonmet Composites & F, Mianyang 621010, Peoples R China





电子邮件地址:XFLiang@swust.edu.cn


基金资助致谢



基金资助机构

授权号



Science Foundation of Southwest University of Science and Technology


11zx7157



Scientific Research Fund of Sichuan Provincial Education Department


14ZA0105

查看基金资助信息   




出版商

ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS


类别 / 分类

研究方向:Materials Science; Nuclear Science & Technology; Mining & Mineral Processing

Web of Science 类别:Materials Science, Multidisciplinary; Nuclear Science & Technology; Mining & Mineral Processing


文献信息

文献类型:Article

语种:English

入藏号: WOS:000341679900031

ISSN: 0022-3115

电子 ISSN: 1873-4820


期刊信息


Impact Factor (影响因子): Journal Citation Reports&reg;


其他信息

IDS 号: AO9MN

Web of Science 核心合集中的 "引用的参考文献": 47

Web of Science 核心合集中的 "被引频次": 0
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