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[资源] 钙钛矿最新综述——钙钛矿作为贵金属催化剂的替代品:梦想和现实

一篇名为“Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality”的综述文章刚刚在chemical review上线,全文77页,参考文献834篇。
钙钛矿太阳能电池在最近几年无疑是所有研究领域中最热的研究分支之一,通常用于太阳能电池的材料为CH3NH3PbI3,属于钙钛矿中一种。
一般来说钙钛矿晶相构成为ABO3型,其中A,B为阳离子,而O代表氧负离子。他们也是异相催化领域研究比较广泛的一类催化剂。钙钛矿的催化研究始于上世纪70年代,报道了其在氧化和NO催化还原反应等方面的优秀的催化性质。
1. Introduction and Background
2. Recent Advances in Perovskite Synthesis: From Large Nano to Small Nano
2.1. Advances in Solid–Solid Processes for Nano-Perovskite Synthesis
2.1.1. Reactive Grinding Synthesis
2.1.2. Microwave Crystallization
2.2. Advances in Solution-Mediated Processes
2.2.1. Classical Hydroxyacid Complexation Route
2.2.2. Autocombustion Processes
2.2.3. Nonaqueous Solvothermal Synthesis Route
2.2.4. Mesostructuration: Nanocasting/Hard Templating as an Efficient Approach
2.2.5. Macrostructuration Approaches
2.3. Conclusions
3. Surface and Bulk Characterization
3.1. Redox Properties and Oxygen Mobility of Perovskites
3.1.1. Redox Properties
3.1.2. Oxygen Mobility
3.2. Acid–Base Surface Properties of Perovskites
4. Oxidation Reactions
4.1. General Trends in Oxidation Reactions over Perovskites
4.2. Low-Temperature Oxidation Reaction: CO Oxidation
4.2.1. Effect of the Material Composition
4.2.2. Mechanism of CO Oxidation and Relationship with Surface and Bulk Properties
4.3. High-Temperature Oxidation Reaction: CH4 Oxidation
4.3.1. Effect of the Material Composition
4.3.2. Mechanism of CH4 Oxidation and Relationship with Surface and Bulk Properties
4.4. Volatile Organic Compounds (VOC) Elimination
4.4.1. Alkanes
4.4.2. Alkenes
4.4.3. Aromatics
4.4.4. Alcohols and Other Oxygenates
4.4.5. Comparison Between Hydrocarbons and Oxygenates
4.4.6. Chlorinated Hydrocarbons
4.4.7. Ammonia and Other N Compounds
4.5. Solid–Solid Reaction: Soot Combustion
4.5.1. Soot Combustion in Oxygen or Air
4.5.2. Simultaneous Removal of Soot and NOx
4.5.3. Kinetics and Mechanisms of Soot Oxidation over Perovskites
4.6. Water Depollution
4.6.1. Wet Peroxide Oxidation
4.6.2. Ozonation and Wet Air Oxidation
4.7. Conclusions
5. Perovskite for Reduction Reactions
5.1. NOx Decomposition
5.1.1. Nitrous Oxide Decomposition
5.1.2. Nitric Oxide Decomposition
5.2. NOx Reduction
5.2.1. NOx Reduction in Continuous Processes (SCR and TWC)
5.2.2. NOx Storage Reduction (NSR)
5.3. Conclusions
6. Perovskites in Selective Oxidation Reactions
6.1. Partial Oxidation of Methane (POM) and Hydrocarbons
6.2. Oxidative Coupling of Methane (OCM)
6.3. Selective Oxidation of Ethane to Ethylene
7. Reforming Reactions for Hydrogen and Syngas Production
7.1. Methane Dry Reforming
7.2. Steam Reforming of Methane
7.3. Other Molecules, Including Short Alcohols, Glycerol, and Renewable Molecules
7.3.1. Steam Reforming of Ethanol
7.3.2. Fuel Reforming
7.4. Conclusions
8. Carbon Nanotube Synthesis as New Catalytic Application
9. General Conclusions and Perspectives钙钛矿最新综述——钙钛矿作为贵金属催化剂的替代品:梦想和现实
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