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wanghao69

гæ (СÓÐÃûÆø)

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ABSTRACT
Recently, the material of castables used  for wall and bottom of steel ladle has  been changed from alumina-spinel to alumina-magnesia because the corrosion
and penetration resistance of the alumina-magnesia castables are mproved more than the alumina-spinel  castables due to the in-situ spinel formation. Regarding the properties of spinel-containing castables, we have carried out laboratory experiments on three types of spinel-containing castables (alumina-spinel, aluminaspinel-
magnesia and alumina-magnesia),and the results have been applied to steel ladle. According to the laboratory experiments the magnesia-containing
castable showed dramatic linear expansion at the over 1200¡æ due to the in-situ spinel formation, and the aluminamagnesia  castables showed the highest
corrosion resistance among three types of castables. However, the field test showed different result. The aluminaspinel castable could maintain stability
without spalling. On the other hand, the alumina-spinel-magnesia could not satisfy the expected life time due to spalling. We can assume that it is due to
the difference in spinel generation speed, which is caused by the reaction between alumina and magnesia on the movable and unmovable surface. One of effective
methods to control the expansion is addition of microsilica. Nonetheless, it is important to control the optimal speed and microsilica content in castables
according to the operational condition.

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