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| we propose that the bare aluminum surface produced by milling will lead to an acid-catalyzed aldol reaction mechanism. The fresh Al surface serves to tautomerize the carbonyl to form the enol complex, and will activate the carbonyl group of another molecule rendering it electrophilic. Being nucleophilic to the a-carbon, the enol will attack the activated carbonyl compound leading to the formation of the aldol structure. |
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RXMCDM: ½ð±Ò+1, ¶àлӦÖú£¡ 2014-07-31 14:40:54
dz²ÝÂþÂþ(RXMCDM´ú·¢): ½ð±Ò+4, ¶àлӦÖú£¡ 2014-08-12 09:13:37
RXMCDM: ½ð±Ò+1, ¶àлӦÖú£¡ 2014-07-31 14:40:54
dz²ÝÂþÂþ(RXMCDM´ú·¢): ½ð±Ò+4, ¶àлӦÖú£¡ 2014-08-12 09:13:37
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