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【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
fuying: 金币+5, ★有帮助 2014-06-12 14:13:30
jssxh: 金币+3, 检索EPI+1, 谢谢参与，请继续关注本版块！ 2014-06-12 16:29:40
Cu(acac)(2)-Catalyzed Synthesis of Functionalized Bis(arylmethyl)zinc Reagents and Their Olefination Reaction with Aromatic Aldehydes
作者:Fu, Y (Fu, Ying)[ 1 ] ; Hu, XM (Hu, Xuemei)[ 1 ] ; Chen, YJ (Chen, Yaojuan)[ 1 ] ; Yang, YS (Yang, Yanshou)[ 1 ] ; Hou, HX (Hou, Hongxia)[ 1 ] ; Hu, YL (Hu, Yulai)[ 1 ]
SYNTHESIS-STUTTGART
卷: 44 期: 7 页: 1030-1036
DOI: 10.1055/s-0031-1289723
出版年: APR 2012
查看期刊信息
摘要
An efficient and facile copper(II) acetylacetonate catalyzed synthesis of functionalized bis(arylmethyl)zinc reagents from arylmethyl halides and their olefination reaction with aromatic aldehydes is reported. Aluminum trichloride was found to be the key ingredient in these reactions and (E)-stilbenes were obtained in high yields.
关键词
作者关键词:aldehyde; zinc; nucleophilic addition; olefination; benzylation
KeyWords Plus OUBLE-BOND FORMATION; ORGANOZINC REAGENTS; CARBONYL-COMPOUNDS; STEREOSELECTIVE-SYNTHESIS; STILBENE DERIVATIVES; ZINC; CHLORIDES; HYDROZINCATION; ACID
作者信息
通讯作者地址: Fu, Y (通讯作者)
显示增强组织信息的名称 NW Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China.
地址:
显示增强组织信息的名称 [ 1 ] NW Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
电子邮件地址:fuying@iccas.ac.cn
基金资助致谢
基金资助机构 授权号
National Natural Science Foundation of China
20962017
Natural Science Foundation of Gansu Province, China
1107RJZA263
Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education
Key laboratory Polymer Materials of Gansu Province (Northwest Normal University)
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出版商
GEORG THIEME VERLAG KG, RUDIGERSTR 14, D-70469 STUTTGART, GERMANY
类别 / 分类
研究方向:Chemistry
Web of Science 类别:Chemistry, Organic
文献信息
文献类型:Article
语种:English
入藏号: WOS:000303104200004
ISSN: 0039-7881
期刊信息
Impact Factor (影响因子): Journal Citation Reports®
其他信息
IDS 号: 929ZJ
Web of Science 核心合集中的 "引用的参考文献": 33
Web of Science 核心合集中的 "被引频次": 1 |
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